Oxygen-tolerant [NiFe]-hydrogenases: the individual and collective importance of supernumerary cysteines at the proximal Fe-S cluster.
An important clue to the mechanism for O(2) tolerance of certain [NiFe]-hydrogenases is the conserved presence of a modified environment around the iron-sulfur cluster that is proximal to the active site. The O(2)-tolerant enzymes contain two cysteines, located at opposite ends of this cluster, whic...
Hlavní autoři: | Lukey, M, Roessler, M, Parkin, A, Evans, R, Davies, R, Lenz, O, Friedrich, B, Sargent, F, Armstrong, F |
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Médium: | Journal article |
Jazyk: | English |
Vydáno: |
2011
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