A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking

An electro-chemo-mechanical phase-field formulation is developed to simulate pitting and stress corrosion in polycrystalline materials. The formulation incorporates dependencies of mechanical properties and corrosion potential on crystallographic orientation. The model considers the formation and ch...

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Main Authors: Makuch, M, Kovacevic, S, Wenman, MR, Martinez-Paneda, E
Format: Journal article
Language:English
Published: Elsevier 2024
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author Makuch, M
Kovacevic, S
Wenman, MR
Martinez-Paneda, E
author_facet Makuch, M
Kovacevic, S
Wenman, MR
Martinez-Paneda, E
author_sort Makuch, M
collection OXFORD
description An electro-chemo-mechanical phase-field formulation is developed to simulate pitting and stress corrosion in polycrystalline materials. The formulation incorporates dependencies of mechanical properties and corrosion potential on crystallographic orientation. The model considers the formation and charging dynamics of an electric double layer through a new general boundary condition for the solution potential. The potential of the model is demonstrated by simulating corrosion in polycrystalline materials with various grain morphology distributions. The results show that incorporating the underlying microstructure yields more extensive defects, faster defect kinetics, and irregular pit and crack shapes relative to a microstructurally-insensitive homogeneous material scenario.
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spelling oxford-uuid:9d0fcbb7-5122-4041-ace5-ac616a0d1fde2024-05-02T14:45:23ZA microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion crackingJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9d0fcbb7-5122-4041-ace5-ac616a0d1fdeEnglishSymplectic ElementsElsevier2024Makuch, MKovacevic, SWenman, MRMartinez-Paneda, EAn electro-chemo-mechanical phase-field formulation is developed to simulate pitting and stress corrosion in polycrystalline materials. The formulation incorporates dependencies of mechanical properties and corrosion potential on crystallographic orientation. The model considers the formation and charging dynamics of an electric double layer through a new general boundary condition for the solution potential. The potential of the model is demonstrated by simulating corrosion in polycrystalline materials with various grain morphology distributions. The results show that incorporating the underlying microstructure yields more extensive defects, faster defect kinetics, and irregular pit and crack shapes relative to a microstructurally-insensitive homogeneous material scenario.
spellingShingle Makuch, M
Kovacevic, S
Wenman, MR
Martinez-Paneda, E
A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title_full A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title_fullStr A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title_full_unstemmed A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title_short A microstructure-sensitive electro-chemo-mechanical phase-field model of pitting and stress corrosion cracking
title_sort microstructure sensitive electro chemo mechanical phase field model of pitting and stress corrosion cracking
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