A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst.
Ethylene polymerisation productivities of tris(pyrazolyl)methane-supported catalysts [Ti(NR){HC(Me2pz)3}Cl2] show a dramatically different dependence on the imido R-group compared to those of their TACN analogues, attributed to differences in fac-N3 donor topology; when treated with AliBu3, the zwit...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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| _version_ | 1826287555772940288 |
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| author | Bigmore, H Dubberley, SR Kranenburg, M Lawrence, S Sealey, A Selby, J Zuideveld, M Cowley, A Mountford, P |
| author_facet | Bigmore, H Dubberley, SR Kranenburg, M Lawrence, S Sealey, A Selby, J Zuideveld, M Cowley, A Mountford, P |
| author_sort | Bigmore, H |
| collection | OXFORD |
| description | Ethylene polymerisation productivities of tris(pyrazolyl)methane-supported catalysts [Ti(NR){HC(Me2pz)3}Cl2] show a dramatically different dependence on the imido R-group compared to those of their TACN analogues, attributed to differences in fac-N3 donor topology; when treated with AliBu3, the zwitterionic tris(pyrazolyl)methide compound [Ti(N-2-C6H4tBu){C(Me2pz)3}Cl(THF)] also acts as a highly active, single site catalyst (TACN = 1,4,7-trimethyltriazacyclononane). |
| first_indexed | 2024-03-07T02:00:27Z |
| format | Journal article |
| id | oxford-uuid:9d320cd6-7c77-4d82-9713-a8790416f3fb |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:00:27Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:9d320cd6-7c77-4d82-9713-a8790416f3fb2022-03-27T00:41:10ZA remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9d320cd6-7c77-4d82-9713-a8790416f3fbEnglishSymplectic Elements at Oxford2006Bigmore, HDubberley, SRKranenburg, MLawrence, SSealey, ASelby, JZuideveld, MCowley, AMountford, PEthylene polymerisation productivities of tris(pyrazolyl)methane-supported catalysts [Ti(NR){HC(Me2pz)3}Cl2] show a dramatically different dependence on the imido R-group compared to those of their TACN analogues, attributed to differences in fac-N3 donor topology; when treated with AliBu3, the zwitterionic tris(pyrazolyl)methide compound [Ti(N-2-C6H4tBu){C(Me2pz)3}Cl(THF)] also acts as a highly active, single site catalyst (TACN = 1,4,7-trimethyltriazacyclononane). |
| spellingShingle | Bigmore, H Dubberley, SR Kranenburg, M Lawrence, S Sealey, A Selby, J Zuideveld, M Cowley, A Mountford, P A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title | A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title_full | A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title_fullStr | A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title_full_unstemmed | A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title_short | A remarkable inversion of structure-activity dependence on imido N-substituents with varying co-ligand topology and the synthesis of a new borate-free zwitterionic polymerisation catalyst. |
| title_sort | remarkable inversion of structure activity dependence on imido n substituents with varying co ligand topology and the synthesis of a new borate free zwitterionic polymerisation catalyst |
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