COEXISTENCE AND PHASE-SEPARATION IN CLUSTERS - FROM THE SMALL TO THE NOT-SO-SMALL REGIME
We generalize the necessary and sufficient conditions for finite systems to exhibit van der Waals-type loops (or "S-bends") in thermodynamic functions. In the infinite limit, such features are forbidden by Van Hove's theorem, and phase separation occurs instead. However, in small syst...
Príomhchruthaitheoirí: | Wales, D, Doye, J |
---|---|
Formáid: | Journal article |
Foilsithe / Cruthaithe: |
1995
|
Míreanna comhchosúla
Míreanna comhchosúla
-
AN ORDER-PARAMETER APPROACH TO COEXISTENCE IN ATOMIC CLUSTERS
de réir: Doye, J, et al.
Foilsithe / Cruthaithe: (1995) -
CALCULATION OF THERMODYNAMIC PROPERTIES OF SMALL LENNARD-JONES CLUSTERS INCORPORATING ANHARMONICITY
de réir: Doye, J, et al.
Foilsithe / Cruthaithe: (1995) -
Theoretical predictions of structure and thermodynamics in the large cluster regime
de réir: Wales, D, et al.
Foilsithe / Cruthaithe: (1996) -
Magic numbers and growth sequences of small face-centred-cubic and decahedral clusters
de réir: Doye, J, et al.
Foilsithe / Cruthaithe: (1995) -
The structure of small lead clusters
de réir: Doye, J, et al.
Foilsithe / Cruthaithe: (2002)