Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.

Single and double substrate insertion into the Ti=N(alpha) bonds of terminal titanium hydrazides.

Nitriles, CO(2) and isocyanates undergo net single or double insertion reactions into the Ti=N(alpha) multiple bonds of terminal titanium hydrazides. These are the first such examples of this type of reactivity for any transition metal hydrazide complex.

Bibliographic Details
Main Authors:	Tiong, P, Schofield, A, Selby, J, Nova, A, Clot, E, Mountford, P
Format:	Journal article
Language:	English
Published:	2010

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