Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
Homogeneous dispersion of microemulsion containing palladium nanoparticles in scCO2 is, for the first time, observed via sapphire window reactor and these particles show an unusual reluctance for double bond hydrogenation of citral aldehyde at hydrophobic end rather than hydrophilic end (high regios...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2004
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| _version_ | 1797085089576779776 |
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| author | Meric, P Yu, K Tsang, S |
| author_facet | Meric, P Yu, K Tsang, S |
| author_sort | Meric, P |
| collection | OXFORD |
| description | Homogeneous dispersion of microemulsion containing palladium nanoparticles in scCO2 is, for the first time, observed via sapphire window reactor and these particles show an unusual reluctance for double bond hydrogenation of citral aldehyde at hydrophobic end rather than hydrophilic end (high regioselectivity) owing to the unique micelle environment in supercritical carbon dioxide that guide a head-on attack of the molecule. |
| first_indexed | 2024-03-07T02:04:12Z |
| format | Journal article |
| id | oxford-uuid:9e686ab4-a370-48dd-98e6-2e9ab190e496 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:04:12Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:9e686ab4-a370-48dd-98e6-2e9ab190e4962022-03-27T00:49:53ZMolecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2 Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9e686ab4-a370-48dd-98e6-2e9ab190e496EnglishSymplectic Elements at Oxford2004Meric, PYu, KTsang, SHomogeneous dispersion of microemulsion containing palladium nanoparticles in scCO2 is, for the first time, observed via sapphire window reactor and these particles show an unusual reluctance for double bond hydrogenation of citral aldehyde at hydrophobic end rather than hydrophilic end (high regioselectivity) owing to the unique micelle environment in supercritical carbon dioxide that guide a head-on attack of the molecule. |
| spellingShingle | Meric, P Yu, K Tsang, S Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2 |
| title | Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
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| title_full | Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
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| title_fullStr | Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
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| title_full_unstemmed | Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
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| title_short | Molecular guided catalytic hydrogenation by micelle-hosted Pd nanoparticle in supercritical CO2
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| title_sort | molecular guided catalytic hydrogenation by micelle hosted pd nanoparticle in supercritical co2 |
| work_keys_str_mv | AT mericp molecularguidedcatalytichydrogenationbymicellehostedpdnanoparticleinsupercriticalco2 AT yuk molecularguidedcatalytichydrogenationbymicellehostedpdnanoparticleinsupercriticalco2 AT tsangs molecularguidedcatalytichydrogenationbymicellehostedpdnanoparticleinsupercriticalco2 |