THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION
The theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of...
| Autori principali: | , , |
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| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
Kluwer Academic Publishers
1990
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| _version_ | 1826287811382214656 |
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| author | Compton, R Fisher, A Tyley, G |
| author_facet | Compton, R Fisher, A Tyley, G |
| author_sort | Compton, R |
| collection | OXFORD |
| description | The theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of characterizing the EC mechanism. A working curve is presented which permits the analysis of experimental data and the deduction of the rate constant for the following chemical reaction. © 1990 Chapman and Hall Ltd. |
| first_indexed | 2024-03-07T02:04:15Z |
| format | Journal article |
| id | oxford-uuid:9e6cd1d3-c13b-4b5c-b9e0-d29a03c5b87e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:04:15Z |
| publishDate | 1990 |
| publisher | Kluwer Academic Publishers |
| record_format | dspace |
| spelling | oxford-uuid:9e6cd1d3-c13b-4b5c-b9e0-d29a03c5b87e2022-03-27T00:49:57ZTHE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTIONJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9e6cd1d3-c13b-4b5c-b9e0-d29a03c5b87eEnglishSymplectic Elements at OxfordKluwer Academic Publishers1990Compton, RFisher, ATyley, GThe theory of EC reactions at a wall-jet electrode is developed using a computational procedure based on the Backwards Implicit Method. In particular, for the case of a reversible electron transfer, it is shown that the variation of the halfwave potential with solution flow rate provides a means of characterizing the EC mechanism. A working curve is presented which permits the analysis of experimental data and the deduction of the rate constant for the following chemical reaction. © 1990 Chapman and Hall Ltd. |
| spellingShingle | Compton, R Fisher, A Tyley, G THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title | THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title_full | THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title_fullStr | THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title_full_unstemmed | THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title_short | THE WALL-JET ELECTRODE AND THE STUDY OF ELECTRODE-REACTION MECHANISMS - THE EC REACTION |
| title_sort | wall jet electrode and the study of electrode reaction mechanisms the ec reaction |
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