Stereospecificity in the silicon tethered alpha-(methyl)allylation of aldehydes.
Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity.
Main Authors: | , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2003
|
Summary: | Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity. |
---|