Stereospecificity in the silicon tethered alpha-(methyl)allylation of aldehydes.

Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity.

Bibliographic Details
Main Authors: Robertson, J, Hall, M, Green, S
Format: Journal article
Language:English
Published: 2003
Description
Summary:Heating E- and Z-crotyl(diphenyl)silyloxy aldehydes, in the absence of an added catalyst, results in stereospecific intramolecular allyl transfer with moderate to high stereoselectivity.