Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].

Structural and theoretical studies of intermolecular dihydrogen bonding in [(C6F5)2(C6Cl5)B]-H···H-[TMP].

The product of the intermolecular 'frustrated Lewis pair' (FLP) B(C6F5)2(C6Cl5)/2,2,6,6-tetramethylpiperidine and H2 has been studied by single-crystal neutron diffraction. This is the first structurally characterised example of a geometrically unconstrained dihydrogen (H···H) bond within...

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Bibliographic Details
Main Authors:	Zaher, H, Ashley, A, Irwin, M, Thompson, A, Gutmann, M, Krämer, T, O'Hare, D
Format:	Journal article
Language:	English
Published:	2013

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