Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors

<p>We describe a new synthetic methodology for the preparation of high quality, emission tuneable InP-based quantum dots (QDs) using a solid, air- and moisture-tolerant primary phosphine as a group-V precursor. This presents a significantly simpler synthetic pathway compared to the state-of-th...

Full description

Bibliographic Details
Main Authors: Wang, Y, Howley, J, Faria, EN, Huang, C, Carter-Searjeant, S, Fairclough, S, Kirkland, A, Davis, JJ, Naz, F, Sajjad, MT, Goicoechea, JM, Green, M
Format: Journal article
Language:English
Published: Royal Society of Chemistry 2023
_version_ 1797112937439035392
author Wang, Y
Howley, J
Faria, EN
Huang, C
Carter-Searjeant, S
Fairclough, S
Kirkland, A
Davis, JJ
Naz, F
Sajjad, MT
Goicoechea, JM
Green, M
author_facet Wang, Y
Howley, J
Faria, EN
Huang, C
Carter-Searjeant, S
Fairclough, S
Kirkland, A
Davis, JJ
Naz, F
Sajjad, MT
Goicoechea, JM
Green, M
author_sort Wang, Y
collection OXFORD
description <p>We describe a new synthetic methodology for the preparation of high quality, emission tuneable InP-based quantum dots (QDs) using a solid, air- and moisture-tolerant primary phosphine as a group-V precursor. This presents a significantly simpler synthetic pathway compared to the state-of-the-art precursors currently employed in phosphide quantum dot synthesis which are volatile, dangerous and air-sensitive,&nbsp;<em>e.g.</em>&nbsp;P(Si(CH<small><sub>3</sub></small>)<small><sub>3</sub></small>)<small><sub>3</sub></small>.</p>
first_indexed 2024-04-09T03:56:13Z
format Journal article
id oxford-uuid:9f8f1ce6-1d3e-4ae9-8dc0-c9b73bc97e92
institution University of Oxford
language English
last_indexed 2024-04-09T03:56:13Z
publishDate 2023
publisher Royal Society of Chemistry
record_format dspace
spelling oxford-uuid:9f8f1ce6-1d3e-4ae9-8dc0-c9b73bc97e922024-03-15T07:02:00ZPhosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductorsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9f8f1ce6-1d3e-4ae9-8dc0-c9b73bc97e92EnglishSymplectic ElementsRoyal Society of Chemistry2023Wang, YHowley, JFaria, ENHuang, CCarter-Searjeant, SFairclough, SKirkland, ADavis, JJNaz, FSajjad, MTGoicoechea, JMGreen, M<p>We describe a new synthetic methodology for the preparation of high quality, emission tuneable InP-based quantum dots (QDs) using a solid, air- and moisture-tolerant primary phosphine as a group-V precursor. This presents a significantly simpler synthetic pathway compared to the state-of-the-art precursors currently employed in phosphide quantum dot synthesis which are volatile, dangerous and air-sensitive,&nbsp;<em>e.g.</em>&nbsp;P(Si(CH<small><sub>3</sub></small>)<small><sub>3</sub></small>)<small><sub>3</sub></small>.</p>
spellingShingle Wang, Y
Howley, J
Faria, EN
Huang, C
Carter-Searjeant, S
Fairclough, S
Kirkland, A
Davis, JJ
Naz, F
Sajjad, MT
Goicoechea, JM
Green, M
Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title_full Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title_fullStr Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title_full_unstemmed Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title_short Phosphinecarboxamide based InZnP QDs – an air tolerant route to luminescent III–V semiconductors
title_sort phosphinecarboxamide based inznp qds an air tolerant route to luminescent iii v semiconductors
work_keys_str_mv AT wangy phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT howleyj phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT fariaen phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT huangc phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT cartersearjeants phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT faircloughs phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT kirklanda phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT davisjj phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT nazf phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT sajjadmt phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT goicoecheajm phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors
AT greenm phosphinecarboxamidebasedinznpqdsanairtolerantroutetoluminescentiiivsemiconductors