All-or-nothing cooperative self-assembly of an annulene sandwich.
Ring-fenced: A 14-component assembly is formed by coordinating 1,4-diazabicyclo[2.2.2]octane (DABCO) to a [12]porphyrin nanoring. The 24 zinc-nitrogen interactions in this sandwich complex lock each conjugated macrocycle into a planar conformation, dramatically sharpening the near-IR absorption band...
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2011
|
| _version_ | 1797085361939152896 |
|---|---|
| author | Sprafke, J Odell, B Claridge, T Anderson, H |
| author_facet | Sprafke, J Odell, B Claridge, T Anderson, H |
| author_sort | Sprafke, J |
| collection | OXFORD |
| description | Ring-fenced: A 14-component assembly is formed by coordinating 1,4-diazabicyclo[2.2.2]octane (DABCO) to a [12]porphyrin nanoring. The 24 zinc-nitrogen interactions in this sandwich complex lock each conjugated macrocycle into a planar conformation, dramatically sharpening the near-IR absorption band. This result highlights the scope of double-strand formation as a way of creating nano-objects with well-defined shapes. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T02:07:53Z |
| format | Journal article |
| id | oxford-uuid:9f9d2624-790e-4e16-b6fd-f69b3b1e8a29 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:07:53Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:9f9d2624-790e-4e16-b6fd-f69b3b1e8a292022-03-27T00:59:15ZAll-or-nothing cooperative self-assembly of an annulene sandwich.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9f9d2624-790e-4e16-b6fd-f69b3b1e8a29EnglishSymplectic Elements at Oxford2011Sprafke, JOdell, BClaridge, TAnderson, HRing-fenced: A 14-component assembly is formed by coordinating 1,4-diazabicyclo[2.2.2]octane (DABCO) to a [12]porphyrin nanoring. The 24 zinc-nitrogen interactions in this sandwich complex lock each conjugated macrocycle into a planar conformation, dramatically sharpening the near-IR absorption band. This result highlights the scope of double-strand formation as a way of creating nano-objects with well-defined shapes. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Sprafke, J Odell, B Claridge, T Anderson, H All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title | All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title_full | All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title_fullStr | All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title_full_unstemmed | All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title_short | All-or-nothing cooperative self-assembly of an annulene sandwich. |
| title_sort | all or nothing cooperative self assembly of an annulene sandwich |
| work_keys_str_mv | AT sprafkej allornothingcooperativeselfassemblyofanannulenesandwich AT odellb allornothingcooperativeselfassemblyofanannulenesandwich AT claridget allornothingcooperativeselfassemblyofanannulenesandwich AT andersonh allornothingcooperativeselfassemblyofanannulenesandwich |