Voltammetric sensing of thiols. The electrocatalytic oxidation of 4-acetamidophenol in the presence of cysteine: a mechanistic rotating disk electrode study

A numerical method is illustrated for the modeling of an important electrocatalytic reaction at the rotating disk electrode (RDE). This reaction, labeled EC2xE, occurs via the following route: A - 2e- ⇌ B, B + X → B-X (k2), B-X - 2e- ⇌ [B-X]2+. The numerical method is based on a finite difference fo...

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Bibliographic Details
Main Authors: Brookes, B, White, P, Lawrence, N, Compton, R
Format: Journal article
Language:English
Published: 2001