Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.

Imidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of...

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Үндсэн зохиолчид: Cormode, D, Murray, S, Cowley, A, Beer, P
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2006
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author Cormode, D
Murray, S
Cowley, A
Beer, P
author_facet Cormode, D
Murray, S
Cowley, A
Beer, P
author_sort Cormode, D
collection OXFORD
description Imidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of strongly complexing sulfate in competitive water-DMSO (5 : 95) solvent mixtures. Cyclic and square wave voltammetric studies demonstrate the receptor's ability to sense a variety of anions electrochemically.
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spelling oxford-uuid:9fc0bb15-16e4-40ea-8b81-dba8b404d2e92022-03-27T02:00:10ZSulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9fc0bb15-16e4-40ea-8b81-dba8b404d2e9EnglishSymplectic Elements at Oxford2006Cormode, DMurray, SCowley, ABeer, PImidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of strongly complexing sulfate in competitive water-DMSO (5 : 95) solvent mixtures. Cyclic and square wave voltammetric studies demonstrate the receptor's ability to sense a variety of anions electrochemically.
spellingShingle Cormode, D
Murray, S
Cowley, A
Beer, P
Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title_full Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title_fullStr Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title_full_unstemmed Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title_short Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
title_sort sulfate selective anion recognition by a novel tetra imidazolium zinc metalloporphyrin receptor
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AT murrays sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor
AT cowleya sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor
AT beerp sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor