Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.
Imidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of...
Үндсэн зохиолчид: | , , , |
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Формат: | Journal article |
Хэл сонгох: | English |
Хэвлэсэн: |
2006
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_version_ | 1826288080703717376 |
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author | Cormode, D Murray, S Cowley, A Beer, P |
author_facet | Cormode, D Murray, S Cowley, A Beer, P |
author_sort | Cormode, D |
collection | OXFORD |
description | Imidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of strongly complexing sulfate in competitive water-DMSO (5 : 95) solvent mixtures. Cyclic and square wave voltammetric studies demonstrate the receptor's ability to sense a variety of anions electrochemically. |
first_indexed | 2024-03-07T02:08:20Z |
format | Journal article |
id | oxford-uuid:9fc0bb15-16e4-40ea-8b81-dba8b404d2e9 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:08:20Z |
publishDate | 2006 |
record_format | dspace |
spelling | oxford-uuid:9fc0bb15-16e4-40ea-8b81-dba8b404d2e92022-03-27T02:00:10ZSulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:9fc0bb15-16e4-40ea-8b81-dba8b404d2e9EnglishSymplectic Elements at Oxford2006Cormode, DMurray, SCowley, ABeer, PImidazolium groups have been successfully incorporated into the structure of a "picket fence" porphyrin molecule to produce a novel tetra-imidazolium zinc metalloporphyrin anion receptor. UV/visible spectroscopic studies reveal that this receptor is selective for sulfate anions, capable of strongly complexing sulfate in competitive water-DMSO (5 : 95) solvent mixtures. Cyclic and square wave voltammetric studies demonstrate the receptor's ability to sense a variety of anions electrochemically. |
spellingShingle | Cormode, D Murray, S Cowley, A Beer, P Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title | Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title_full | Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title_fullStr | Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title_full_unstemmed | Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title_short | Sulfate selective anion recognition by a novel tetra-imidazolium zinc metalloporphyrin receptor. |
title_sort | sulfate selective anion recognition by a novel tetra imidazolium zinc metalloporphyrin receptor |
work_keys_str_mv | AT cormoded sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor AT murrays sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor AT cowleya sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor AT beerp sulfateselectiveanionrecognitionbyanoveltetraimidazoliumzincmetalloporphyrinreceptor |