A time resolved, in-situ X-ray diffraction study of the de-intercalation of anions and lithium cations from [LiAl2(OH)(6)](n)X center dot qH(2)O (X = Cl-, Br-, NO3-, SO42-)
The layered double hydroxides (LDHs), [LiAl2(OH) 6]nX·qH2O (Xn- = CP -, Br-, NO3,- SO42-) spontaneously lose both Li+ cations and Xn- anions to give crystalline Al(OH)3 on stirring in water. The kinetics of this topochemical de-intercalation reaction have been studied using time-resolved, in-situ en...
Egile Nagusiak: | Tarasov, K, Isupov, V, Chupakhina, L, O'Hare, D |
---|---|
Formatua: | Journal article |
Hizkuntza: | English |
Argitaratua: |
2004
|
Antzeko izenburuak
-
Synthesis and structure of the gibbsite intercalation compounds [LiAl2(OH)(6)]X {X=Cl, Br, NO3} and [LiAl2(OH)(6)]Cl center dot H2O using synchrotron X-ray and neutron powder diffraction
nork: Besserguenev, A, et al.
Argitaratua: (1997) -
Factors influencing staging during anion-exchange intercalation into [LiAl2(OH)(6)]X center dot mH(2)O (X = Cl-, Br-, NO3-)
nork: Williams, G, et al.
Argitaratua: (2005) -
Selective intercalation of chlorophenoxyacetates into the layered double hydroxide [LiAl2(OH)(6)]Cl center dot xH(2)O
nork: Ragavan, A, et al.
Argitaratua: (2006) -
Intercalation and controlled release of 2,4-dichlorophenoxyacetic acid using rhombohedral [LiAl2(OH)(6)]Cl center dot xH(2)O
nork: Ragavan, A, et al.
Argitaratua: (2006) -
Isomer selective ion-exchange intercalation of nitrophenolates into the layered double hydroxide [LiAl2(OH)(6)]Cl center dot xH(2)O
nork: Ragavan, A, et al.
Argitaratua: (2006)