A microwave study of the hetero-chiral dimer of butan-2-ol
The first observation of a rotationally resolved spectrum for a dimeric complex of chiral molecules is reported. The complex in question is a hydrogen-bonded dimer of butan-2-ol and is shown to be hetero-chiral in composition. The rotational constants and components of the dipole moment agree well w...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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2001
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| _version_ | 1826288250219659264 |
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| author | King, A Howard, B |
| author_facet | King, A Howard, B |
| author_sort | King, A |
| collection | OXFORD |
| description | The first observation of a rotationally resolved spectrum for a dimeric complex of chiral molecules is reported. The complex in question is a hydrogen-bonded dimer of butan-2-ol and is shown to be hetero-chiral in composition. The rotational constants and components of the dipole moment agree well with the predictions of an ab initio study, the initial results of which are also reported. The ability of chiral species to form diastereoisomeric hetero- and homo-chiral complexes is thus given strong support. © 2001 Elsevier Science B.V. |
| first_indexed | 2024-03-07T02:10:52Z |
| format | Journal article |
| id | oxford-uuid:a097ce1f-f9eb-42dc-84f8-5c7cc7fae85a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:10:52Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:a097ce1f-f9eb-42dc-84f8-5c7cc7fae85a2022-03-27T02:06:36ZA microwave study of the hetero-chiral dimer of butan-2-olJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a097ce1f-f9eb-42dc-84f8-5c7cc7fae85aEnglishSymplectic Elements at Oxford2001King, AHoward, BThe first observation of a rotationally resolved spectrum for a dimeric complex of chiral molecules is reported. The complex in question is a hydrogen-bonded dimer of butan-2-ol and is shown to be hetero-chiral in composition. The rotational constants and components of the dipole moment agree well with the predictions of an ab initio study, the initial results of which are also reported. The ability of chiral species to form diastereoisomeric hetero- and homo-chiral complexes is thus given strong support. © 2001 Elsevier Science B.V. |
| spellingShingle | King, A Howard, B A microwave study of the hetero-chiral dimer of butan-2-ol |
| title | A microwave study of the hetero-chiral dimer of butan-2-ol |
| title_full | A microwave study of the hetero-chiral dimer of butan-2-ol |
| title_fullStr | A microwave study of the hetero-chiral dimer of butan-2-ol |
| title_full_unstemmed | A microwave study of the hetero-chiral dimer of butan-2-ol |
| title_short | A microwave study of the hetero-chiral dimer of butan-2-ol |
| title_sort | microwave study of the hetero chiral dimer of butan 2 ol |
| work_keys_str_mv | AT kinga amicrowavestudyoftheheterochiraldimerofbutan2ol AT howardb amicrowavestudyoftheheterochiraldimerofbutan2ol AT kinga microwavestudyoftheheterochiraldimerofbutan2ol AT howardb microwavestudyoftheheterochiraldimerofbutan2ol |