Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors.
Intramolecular pyrylium ylide-alkene cyclizations provide control of the absolute stereochemistry at the crucial C-19 angular methyl group, and leads to bicyclo[5.4.0 3,8]undecenones that contain the structral elements of the B/C rings of the taxanes.
| Main Authors: | , , , , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
1996
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| _version_ | 1797085645463617536 |
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| author | Bauta, W Booth, J Bos, M DeLuca, M Diorazio, L Donohoe, T Frost, C Magnus, N Magnus, P Mendoza, J Pye, P Tarrant, J Thom, S Ujjainwalla, F |
| author_facet | Bauta, W Booth, J Bos, M DeLuca, M Diorazio, L Donohoe, T Frost, C Magnus, N Magnus, P Mendoza, J Pye, P Tarrant, J Thom, S Ujjainwalla, F |
| author_sort | Bauta, W |
| collection | OXFORD |
| description | Intramolecular pyrylium ylide-alkene cyclizations provide control of the absolute stereochemistry at the crucial C-19 angular methyl group, and leads to bicyclo[5.4.0 3,8]undecenones that contain the structral elements of the B/C rings of the taxanes. |
| first_indexed | 2024-03-07T02:11:25Z |
| format | Journal article |
| id | oxford-uuid:a0c763ed-b8b9-476f-8cd6-6b7c3bc805b9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:11:25Z |
| publishDate | 1996 |
| record_format | dspace |
| spelling | oxford-uuid:a0c763ed-b8b9-476f-8cd6-6b7c3bc805b92022-03-27T02:08:05ZTaxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a0c763ed-b8b9-476f-8cd6-6b7c3bc805b9EnglishSymplectic Elements at Oxford1996Bauta, WBooth, JBos, MDeLuca, MDiorazio, LDonohoe, TFrost, CMagnus, NMagnus, PMendoza, JPye, PTarrant, JThom, SUjjainwalla, FIntramolecular pyrylium ylide-alkene cyclizations provide control of the absolute stereochemistry at the crucial C-19 angular methyl group, and leads to bicyclo[5.4.0 3,8]undecenones that contain the structral elements of the B/C rings of the taxanes. |
| spellingShingle | Bauta, W Booth, J Bos, M DeLuca, M Diorazio, L Donohoe, T Frost, C Magnus, N Magnus, P Mendoza, J Pye, P Tarrant, J Thom, S Ujjainwalla, F Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title | Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title_full | Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title_fullStr | Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title_full_unstemmed | Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title_short | Taxane diterpenes .1. Control of relative and absolute stereochemistry in intramolecular pyrylium ylide-alkene cyclizations for the synthesis of taxol precursors. |
| title_sort | taxane diterpenes 1 control of relative and absolute stereochemistry in intramolecular pyrylium ylide alkene cyclizations for the synthesis of taxol precursors |
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