New cationic palladium (II) and rhodium (I) complexes of [Ph2PCH2C(Ph)=N(2,6-Me2C6H3)]
Treatment of the bulky iminophosphine ligand [Ph2PCH 2C(Ph)=N(2,6-Me2C6H3)] (L) with [M(CH3CN)2(ligand)]+n, where for M = Pd(II): ligand = η3-allyl, n = 1, and for M = Rh(I), ligand: 2(C 2H4), 2(CO) or cod, n = 0, yields the mono-cationic iminophosphine complexes [Pd(η3-C3H 5)(L)][BF4] (1), [Rh(cod)...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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