New cationic palladium (II) and rhodium (I) complexes of [Ph2PCH2C(Ph)=N(2,6-Me2C6H3)]

New cationic palladium (II) and rhodium (I) complexes of [Ph2PCH2C(Ph)=N(2,6-Me2C6H3)]

Treatment of the bulky iminophosphine ligand [Ph2PCH 2C(Ph)=N(2,6-Me2C6H3)] (L) with [M(CH3CN)2(ligand)]+n, where for M = Pd(II): ligand = η3-allyl, n = 1, and for M = Rh(I), ligand: 2(C 2H4), 2(CO) or cod, n = 0, yields the mono-cationic iminophosphine complexes [Pd(η3-C3H 5)(L)][BF4] (1), [Rh(cod)...

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Bibliographic Details
Main Authors:	Pascu, S, Coleman, K, Cowley, A, Green, M, Rees, N
Format:	Journal article
Language:	English
Published:	2005

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