Dual catalytic enantioselective desymmetrization of allene-tethered cyclohexanones

Dual catalytic enantioselective desymmetrization of allene-tethered cyclohexanones

The construction of enantioenriched azabicyclo[3.3.1]nonan-6-one heterocycles via an enantioselective desymmetrization of allene-linked cyclohexanones, enabled through a dual catalytic system, that provides synchronous activation of the cyclohexanone with a chiral prolinamide and the allene with a c...

書誌詳細
主要な著者:	Zhang, L, Yamazaki, K, Leitch, JA, Manzano, R, Atkinson, AM, Hamlin, TA, Dixon, DJ
フォーマット:	Journal article
言語:	English
出版事項:	Royal Society of Chemistry 2020

類似資料

Enantioselective total synthesis of (−)-Himalensine A via a palladium and 4-hydroxyproline co-catalyzed desymmetrization of vinyl-bromide-tethered cyclohexanones
著者:: Kučera, R, 等
出版事項: (2023)

Enantioselective silver and amine co-catalyzed desymmetrizing cycloisomerization of alkyne-linked cyclohexanones
著者:: Manzano, R, 等
出版事項: (2017)

Catalytic enantioselective nucleophilic desymmetrization of phosphonate esters
著者:: Formica, M, 等
出版事項: (2023)

Second generation catalytic enantioselective nucleophilic desymmetrization at P(V): improved generality, efficiency and modularity
著者:: Formica, M, 等
出版事項: (2024)

Second generation catalytic enantioselective nucleophilic desymmetrization at P(V): improved generality, efficiency and modularity
著者:: Formica, M, 等
出版事項: (2024)

Enantioselective desymmetrization of prochiral cyclohexanones by organocatalytic intramolecular Michael additions to α,β-unsaturated esters
著者:: Gammack Yamagata, A, 等
出版事項: (2015)

A new organocatalytic desymmetrization reaction enables the enantioselective total synthesis of madangamine E
著者:: Shiomi, S, 等
出版事項: (2022)

Bifunctional iminophosphorane catalyzed amide enolization for enantioselective cyclohexadienone desymmetrization.
著者:: Poh, CYX, 等
出版事項: (2023)

Catalytic enantioselective intramolecular oxa-Michael reaction to α,β-unsaturated esters and amides
著者:: Su, G, 等
出版事項: (2023)

Organocatalyzed enantioselective desymmetrization of aziridines and epoxides
著者:: Ping-An Wang
出版事項: (2013-08-01)

Dual amine and palladium catalysis in diastereo- and enantioselective allene carbocyclization reactions.
著者:: Li, M, 等
出版事項: (2012)

Sequential desymmetrization-fluorination: enantioselective synthesis of fluorinated cyclitols.
著者:: Purser, S, 等
出版事項: (2006)

Catalytic Enantioselective Synthesis of Axially Chiral Diaryl Ethers Via Asymmetric Povarov Reaction Enabled Desymmetrization
著者:: Zidan Ye, 等
出版事項: (2024-09-01)

Aziridinations of tethered allenes
著者:: Feast, GC
出版事項: (2011)

Catalytic enantioselective construction of axial chirality in 1,3-disubstituted allenes
著者:: Shihua Song, 等
出版事項: (2019-01-01)

Palladium mediated enantioselective desymmetrization of meso 1,1-dihaloalkenes.
著者:: Willis, M, 等
出版事項: (2000)

Bicarbonate-binding catalysis for the enantioselective desymmetrization of keto sulfonium salts
著者:: José Alemán, 等
出版事項: (2024-06-01)

Bifunctional iminophosphorane-catalyzed enantioselective sulfa-michael addition to unactivated α,β-unsaturated amides
著者:: Rozsar, D, 等
出版事項: (2022)

Functionalized bicyclo[3.3.0]octanes by enantioselective transannular desymmetrization.
著者:: Hodgson, D, 等
出版事項: (2001)

Bisguanidinium-catalyzed remote enantioselective desymmetrization with 1,2-acyl shift
著者:: Chen, Wenchao, 等
出版事項: (2024)

Enantioselective desymmetrization of cyclohexadienones via an intramolecular Rauhut–Currier reaction of allenoates
著者:: Weijun Yao, 等
出版事項: (2016-10-01)

Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
著者:: Byrne, S, 等
出版事項: (2010)

Pericyclic rearrangements of tethered allene azides
著者:: Zhurakovskyi, O, 等
出版事項: (2012)

Enantioselective access to isoquinuclidines by tropenone desymmetrization and homoallylic radical rearrangement: synthesis of (+)-ibogamine.
著者:: Hodgson, D, 等
出版事項: (2005)

Enantioselective biocatalytic desymmetrization for synthesis of enantiopure cis-3,4-disubstituted pyrrolidines
著者:: Hui-Juan Hu, 等
出版事項: (2021-08-01)

ORGN 743-Palladium-catalyzed enantioselective desymmetrization for the total synthesis of hodgkinsine and related structures
著者:: Durbin, M, 等
出版事項: (2006)

Catalytic enantioselective intermolecular hydroacylation: rhodium-catalyzed combination of beta-S-aldehydes and 1,3-disubstituted allenes.
著者:: Osborne, J, 等
出版事項: (2008)

Switchable, reagent-controlled diastereodivergent photocatalytic carbocyclisation of imine-derived α-amino radicals
著者:: Maitland, JAP, 等
出版事項: (2021)

Access to planar chiral ferrocenes via N-heterocyclic carbene-catalyzed enantioselective desymmetrization reactions
著者:: Lv, Xiaokang, 等
出版事項: (2022)

Nickel(II)/BINOL-catalyzed enantioselective C–H activation via desymmetrization and kinetic resolution
著者:: Qi-Jun Yao, 等
出版事項: (2024-08-01)

Chiral Pentacarboxycyclopentadiene-Based Brønsted Acid-Catalyzed Enantioselective Desymmetrization of Meso-Epoxides by 2‑Mercaptobenzothiazoles
著者:: Chao Yuan, 等
出版事項: (2018-06-01)

A bifunctional iminophosphorane squaramide catalyzed enantioselective synthesis of hydroquinazolines via intramolecular aza-Michael reaction to α,β-unsaturated esters
著者:: Su, G, 等
出版事項: (2021)

Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct
著者:: Liu, Richard, 等
出版事項: (2020)

Applications of planar-chiral phosphaferrocene-oxazolines in asymmetric catalysis and enantioselective desymmetrization by carbon nucleophiles in the presence of chiral ligands
著者:: Shintani, Ryo, 1976-
出版事項: (2006)

Construction of boron-stereogenic compounds via enantioselective Cu-catalyzed desymmetric B–H bond insertion reaction
著者:: Guan Zhang, 等
出版事項: (2022-05-01)

One-pot catalytic enantioselective synthesis of 2-pyrazolines
著者:: Thomson, C, 等
出版事項: (2019)

Cyclohexanone and methylcyclohexanone/
出版事項: (1977)

Highly selective self-condensation of cyclohexanone: the distinct catalytic behaviour of HRF5015
著者:: Xiujing Peng, 等
出版事項: (2020-10-01)

Enantioselective synthesis of inherently chiral sulfur-containing calix[4]arenes via chiral sulfide catalyzed desymmetrizing aromatic sulfenylation
著者:: Xin-Yu Zhang, 等
出版事項: (2024-11-01)

Catalytic enantioselective electrocyclic cascades
著者:: Maciver, E, 等
出版事項: (2011)