A PLATINUM-LINKED CYCLIC PORPHYRIN TRIMER

A cyclic trimeric porphyrin host is synthesised from monomer via alkyne-platinum-alkyne linkages; binding of the octahedral aluminum tris[3-(4-pyridyl)acetylacetonate] guest ligand into the complementary cavity of the host induces an asymmetry, which is readily detected by NMR spectroscopy.

Մատենագիտական մանրամասներ
Հիմնական հեղինակներ: Mackay, L, Anderson, H, Sanders, J
Ձևաչափ: Journal article
Լեզու:English
Հրապարակվել է: 1992
Նկարագրություն
Ամփոփում:A cyclic trimeric porphyrin host is synthesised from monomer via alkyne-platinum-alkyne linkages; binding of the octahedral aluminum tris[3-(4-pyridyl)acetylacetonate] guest ligand into the complementary cavity of the host induces an asymmetry, which is readily detected by NMR spectroscopy.