A monomeric organolithium compound containing a free pyramidal carbanion in solution and in the solid state.

A suitable bridle, created by intramolecular chelation of the Li cation, and lack of π delocalization, yielded the first monomeric lithium organyl compound containing an unassociated tetrahedral carbanionic center (see picture). The zwitterionic structure found in the solid state is preserved in sol...

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التفاصيل البيبلوغرافية
المؤلفون الرئيسيون: Breher, F, Grunenberg, J, Lawrence, S, Mountford, P, Rüegger, H
التنسيق: Journal article
اللغة:English
منشور في: 2004