Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions.
The layered nitride Sr11Ge4N6 contains Ge4- Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [Ge(II)N2]4- ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and -4.
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Format: | Journal article |
Sprache: | English |
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2005
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author | Gál, Z Clarke, S |
author_facet | Gál, Z Clarke, S |
author_sort | Gál, Z |
collection | OXFORD |
description | The layered nitride Sr11Ge4N6 contains Ge4- Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [Ge(II)N2]4- ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and -4. |
first_indexed | 2024-03-07T02:20:25Z |
format | Journal article |
id | oxford-uuid:a3b80b7f-a560-442f-b21f-85cea18e667b |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:20:25Z |
publishDate | 2005 |
record_format | dspace |
spelling | oxford-uuid:a3b80b7f-a560-442f-b21f-85cea18e667b2022-03-27T02:28:58ZSr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a3b80b7f-a560-442f-b21f-85cea18e667bEnglishSymplectic Elements at Oxford2005Gál, ZClarke, SThe layered nitride Sr11Ge4N6 contains Ge4- Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [Ge(II)N2]4- ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and -4. |
spellingShingle | Gál, Z Clarke, S Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title | Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title_full | Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title_fullStr | Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title_full_unstemmed | Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title_short | Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [Ge(II)N2]4- ions. |
title_sort | sr11ge4n6 a new nitride composed of gen2sr7 4 antiperovskite type slabs and sr4ge 4 layers separated by sheets of bent ge ii n2 4 ions |
work_keys_str_mv | AT galz sr11ge4n6anewnitridecomposedofgen2sr74antiperovskitetypeslabsandsr4ge4layersseparatedbysheetsofbentgeiin24ions AT clarkes sr11ge4n6anewnitridecomposedofgen2sr74antiperovskitetypeslabsandsr4ge4layersseparatedbysheetsofbentgeiin24ions |