Chiral recognition in contact ion-pairs; observation, characterization and analysis

Chiral ion-pairs are playing an increasingly important role in asymmetric catalysis. In order to understand the source of molecular recognition, a simple model system based on a BINAP-Rh(dialkene) cation and a BINOL borate anion was studied for both diastereomeric forms. It was discovered that one o...

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Main Authors: Raskatov, J, Thompson, A, Cowley, A, Claridge, T, Brown, J
格式: Journal article
语言:English
出版: 2013