Platinum complexes featuring terminally bound Ga(+) and In(+) ions.
(Chemical Equation Presented) Alone at the apex: The first metal complexes with Ga+ or In+ cations as terminally bound ligands have recently been synthesized. Structural and computational studies suggest a Lewis acid/base Pt-Ga interaction for [GaPt(GaCp*)4]+ (1; Pt blue, Ga violet, C gray; ArF = C6...
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| Formato: | Journal article |
| Idioma: | English |
| Publicado em: |
2006
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| _version_ | 1826288936636383232 |
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| author | Aldridge, S |
| author_facet | Aldridge, S |
| author_sort | Aldridge, S |
| collection | OXFORD |
| description | (Chemical Equation Presented) Alone at the apex: The first metal complexes with Ga+ or In+ cations as terminally bound ligands have recently been synthesized. Structural and computational studies suggest a Lewis acid/base Pt-Ga interaction for [GaPt(GaCp*)4]+ (1; Pt blue, Ga violet, C gray; ArF = C6H3-(CF 3)2-3,5). The Group 13 cation therefore functions as an acceptor ligand, with significant components of both σ and π symmetry contributing to the Pt-Ga linkage. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T02:21:16Z |
| format | Journal article |
| id | oxford-uuid:a3fe4021-ca7e-4d03-9d4f-00c6d55cf2a8 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:21:16Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:a3fe4021-ca7e-4d03-9d4f-00c6d55cf2a82022-03-27T02:30:55ZPlatinum complexes featuring terminally bound Ga(+) and In(+) ions.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a3fe4021-ca7e-4d03-9d4f-00c6d55cf2a8EnglishSymplectic Elements at Oxford2006Aldridge, S(Chemical Equation Presented) Alone at the apex: The first metal complexes with Ga+ or In+ cations as terminally bound ligands have recently been synthesized. Structural and computational studies suggest a Lewis acid/base Pt-Ga interaction for [GaPt(GaCp*)4]+ (1; Pt blue, Ga violet, C gray; ArF = C6H3-(CF 3)2-3,5). The Group 13 cation therefore functions as an acceptor ligand, with significant components of both σ and π symmetry contributing to the Pt-Ga linkage. © 2006 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Aldridge, S Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title | Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title_full | Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title_fullStr | Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title_full_unstemmed | Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title_short | Platinum complexes featuring terminally bound Ga(+) and In(+) ions. |
| title_sort | platinum complexes featuring terminally bound ga and in ions |
| work_keys_str_mv | AT aldridges platinumcomplexesfeaturingterminallyboundgaandinions |