Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
Compared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most ef...
Main Authors: | , , |
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Format: | Journal article |
Language: | English |
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2014
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author | Gan, P Foord, J Compton, R |
author_facet | Gan, P Foord, J Compton, R |
author_sort | Gan, P |
collection | OXFORD |
description | Compared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most efficient among several ionic liquids investigated. Such preconcentration allowed a [C8py][PF6]-multiwalled carbon nanotubes (MWCNTs) (95:5w/w) composite electrode to be useful for adsorptive stripping voltammetry. Screen-printed electrodes modified with [C8py][PF6]-MWCNTs were developed and were able to achieve high sensitivity during adsorptive stripping voltammetric measurements under optimised conditions. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
first_indexed | 2024-03-07T02:21:47Z |
format | Journal article |
id | oxford-uuid:a42e9170-5b19-41cf-bbfb-aa191c86e123 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:21:47Z |
publishDate | 2014 |
record_format | dspace |
spelling | oxford-uuid:a42e9170-5b19-41cf-bbfb-aa191c86e1232022-03-27T02:32:09ZIonic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping VoltammetryJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a42e9170-5b19-41cf-bbfb-aa191c86e123EnglishSymplectic Elements at Oxford2014Gan, PFoord, JCompton, RCompared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most efficient among several ionic liquids investigated. Such preconcentration allowed a [C8py][PF6]-multiwalled carbon nanotubes (MWCNTs) (95:5w/w) composite electrode to be useful for adsorptive stripping voltammetry. Screen-printed electrodes modified with [C8py][PF6]-MWCNTs were developed and were able to achieve high sensitivity during adsorptive stripping voltammetric measurements under optimised conditions. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
spellingShingle | Gan, P Foord, J Compton, R Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title | Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title_full | Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title_fullStr | Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title_full_unstemmed | Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title_short | Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry |
title_sort | ionic liquid carbon nanotube modified screen printed electrodes and their potential for adsorptive stripping voltammetry |
work_keys_str_mv | AT ganp ionicliquidcarbonnanotubemodifiedscreenprintedelectrodesandtheirpotentialforadsorptivestrippingvoltammetry AT foordj ionicliquidcarbonnanotubemodifiedscreenprintedelectrodesandtheirpotentialforadsorptivestrippingvoltammetry AT comptonr ionicliquidcarbonnanotubemodifiedscreenprintedelectrodesandtheirpotentialforadsorptivestrippingvoltammetry |