Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry

Compared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most ef...

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Main Authors: Gan, P, Foord, J, Compton, R
Format: Journal article
Language:English
Published: 2014
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author Gan, P
Foord, J
Compton, R
author_facet Gan, P
Foord, J
Compton, R
author_sort Gan, P
collection OXFORD
description Compared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most efficient among several ionic liquids investigated. Such preconcentration allowed a [C8py][PF6]-multiwalled carbon nanotubes (MWCNTs) (95:5w/w) composite electrode to be useful for adsorptive stripping voltammetry. Screen-printed electrodes modified with [C8py][PF6]-MWCNTs were developed and were able to achieve high sensitivity during adsorptive stripping voltammetric measurements under optimised conditions. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
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spelling oxford-uuid:a42e9170-5b19-41cf-bbfb-aa191c86e1232022-03-27T02:32:09ZIonic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping VoltammetryJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a42e9170-5b19-41cf-bbfb-aa191c86e123EnglishSymplectic Elements at Oxford2014Gan, PFoord, JCompton, RCompared with paraffin oil, the use of ionic liquids as a binder in carbon paste type electrodes was shown to greatly enhance the accumulation of analytes, as illustrated with 17α-ethynylestradiol as a model. The ionic "liquid" n-octyl-pyridinium hexafluorophosphate [C8py][PF6] was most efficient among several ionic liquids investigated. Such preconcentration allowed a [C8py][PF6]-multiwalled carbon nanotubes (MWCNTs) (95:5w/w) composite electrode to be useful for adsorptive stripping voltammetry. Screen-printed electrodes modified with [C8py][PF6]-MWCNTs were developed and were able to achieve high sensitivity during adsorptive stripping voltammetric measurements under optimised conditions. © 2014 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.
spellingShingle Gan, P
Foord, J
Compton, R
Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title_full Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title_fullStr Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title_full_unstemmed Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title_short Ionic Liquid-Carbon Nanotube Modified Screen-Printed Electrodes and Their Potential for Adsorptive Stripping Voltammetry
title_sort ionic liquid carbon nanotube modified screen printed electrodes and their potential for adsorptive stripping voltammetry
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AT foordj ionicliquidcarbonnanotubemodifiedscreenprintedelectrodesandtheirpotentialforadsorptivestrippingvoltammetry
AT comptonr ionicliquidcarbonnanotubemodifiedscreenprintedelectrodesandtheirpotentialforadsorptivestrippingvoltammetry