Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes

Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer...

Cur síos iomlán

Sonraí bibleagrafaíochta
Príomhchruthaitheoirí: Compton, R, Marken, F, Rebbitt, T
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 1996
Cur síos
Achoimre:Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes.