Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes
Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer...
| Hoofdauteurs: | , , |
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| Formaat: | Journal article |
| Taal: | English |
| Gepubliceerd in: |
1996
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| _version_ | 1826289034668802048 |
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| author | Compton, R Marken, F Rebbitt, T |
| author_facet | Compton, R Marken, F Rebbitt, T |
| author_sort | Compton, R |
| collection | OXFORD |
| description | Voltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes. |
| first_indexed | 2024-03-07T02:22:45Z |
| format | Journal article |
| id | oxford-uuid:a485647e-d89f-4c6e-b213-25151a61baae |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:22:45Z |
| publishDate | 1996 |
| record_format | dspace |
| spelling | oxford-uuid:a485647e-d89f-4c6e-b213-25151a61baae2022-03-27T02:34:20ZSonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a485647e-d89f-4c6e-b213-25151a61baaeEnglishSymplectic Elements at Oxford1996Compton, RMarken, FRebbitt, TVoltammetric measurements of the rates of fast homogeneous chemical reactions coupled to heterogeneous electron transfer at macroelectrodes are demonstrated for two systems, the reductive dehalogenations of ortho-bromonitrobenzene and of 3-bromobenzophenone, by the use of power ultrasound to confer fast mass-transport properties so giving the electrodes the kinetic timescale of microelectrodes. |
| spellingShingle | Compton, R Marken, F Rebbitt, T Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title | Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title_full | Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title_fullStr | Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title_full_unstemmed | Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title_short | Sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics: Making macroelectrodes behave like microelectrodes |
| title_sort | sonovoltammetric measurement of the rates of electrode processes with fast coupled homogeneous kinetics making macroelectrodes behave like microelectrodes |
| work_keys_str_mv | AT comptonr sonovoltammetricmeasurementoftheratesofelectrodeprocesseswithfastcoupledhomogeneouskineticsmakingmacroelectrodesbehavelikemicroelectrodes AT markenf sonovoltammetricmeasurementoftheratesofelectrodeprocesseswithfastcoupledhomogeneouskineticsmakingmacroelectrodesbehavelikemicroelectrodes AT rebbittt sonovoltammetricmeasurementoftheratesofelectrodeprocesseswithfastcoupledhomogeneouskineticsmakingmacroelectrodesbehavelikemicroelectrodes |