Generation of a π-Bonded Isomer of [P4]4− by Aluminyl Reduction of White Phosphorus and its Ammonolysis to PH3

By employing the highly reducing aluminyl complex [K{(NON)Al}]<sub>2</sub> (NON=4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene), we demonstrate the controlled formation of P<sub>4</sub> <sup>2-</sup&...

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Bibliographic Details
Main Authors: Roy, MMD, Heilmann, A, Ellwanger, MA, Aldridge, S
Format: Journal article
Language:English
Published: Wiley 2021