Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid
Electrochemical hydrogenolysis has been demonstrated in a room temperature ionic liquid (RTIL) for the first time. Reduction of H[NTf2] at a Pd microelectrode in the RTIL 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) leads to the reversible formation of adsorbed and...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2010
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| _version_ | 1826289088267812864 |
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| author | Meng, Y Aldous, L Compton, R |
| author_facet | Meng, Y Aldous, L Compton, R |
| author_sort | Meng, Y |
| collection | OXFORD |
| description | Electrochemical hydrogenolysis has been demonstrated in a room temperature ionic liquid (RTIL) for the first time. Reduction of H[NTf2] at a Pd microelectrode in the RTIL 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) leads to the reversible formation of adsorbed and absorbed hydrogen (Pd/H). Hydrogenation of N,N′-bis(benzyloxycarbonyl)-l-lysine was observed to proceed rapidly, monitored by the consumption of Pd/H. In addition, the electrolysis of adventitious H2O to form Pd/H is noted. © The Royal Society of Chemistry 2010. |
| first_indexed | 2024-03-07T02:23:34Z |
| format | Journal article |
| id | oxford-uuid:a4cd1fd9-e1b8-485c-b967-8826df75f576 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:23:34Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:a4cd1fd9-e1b8-485c-b967-8826df75f5762022-03-27T02:36:14ZHydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquidJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a4cd1fd9-e1b8-485c-b967-8826df75f576EnglishSymplectic Elements at Oxford2010Meng, YAldous, LCompton, RElectrochemical hydrogenolysis has been demonstrated in a room temperature ionic liquid (RTIL) for the first time. Reduction of H[NTf2] at a Pd microelectrode in the RTIL 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C2mim][NTf2]) leads to the reversible formation of adsorbed and absorbed hydrogen (Pd/H). Hydrogenation of N,N′-bis(benzyloxycarbonyl)-l-lysine was observed to proceed rapidly, monitored by the consumption of Pd/H. In addition, the electrolysis of adventitious H2O to form Pd/H is noted. © The Royal Society of Chemistry 2010. |
| spellingShingle | Meng, Y Aldous, L Compton, R Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title | Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title_full | Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title_fullStr | Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title_full_unstemmed | Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title_short | Hydrogenolysis without hydrogen gas: hydrogen loaded palladium electrodes by electrolysis of H[NTf2] in a room temperature ionic liquid |
| title_sort | hydrogenolysis without hydrogen gas hydrogen loaded palladium electrodes by electrolysis of h ntf2 in a room temperature ionic liquid |
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