Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals
The use of the channel flow cell for ultraviolet-visible (UV-vis) spectroelectrochemical experiments has been developed to determine the diffusion coefficients of electrogenerated species by means of monitoring the transient absorbance response resulting from a potential step at a working electrode...
| Main Authors: | , , , |
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| 格式: | Journal article |
| 語言: | English |
| 出版: |
1997
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| _version_ | 1826289100759498752 |
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| author | Wang, R Tam, K Marken, F Compton, R |
| author_facet | Wang, R Tam, K Marken, F Compton, R |
| author_sort | Wang, R |
| collection | OXFORD |
| description | The use of the channel flow cell for ultraviolet-visible (UV-vis) spectroelectrochemical experiments has been developed to determine the diffusion coefficients of electrogenerated species by means of monitoring the transient absorbance response resulting from a potential step at a working electrode immediately upstream of the incident spectrophotometric beam. The technique is applied to measure the diffusion coefficient of tris(4-bromophenyl)amine (TBPA) radical cation in acetonitrile at 25°C. It is shown that the diffusion coefficient of electrogenerated TBPA radical cation (1.64 ± 0.02 × 10-5 cm-2 s-1) is very close to that of the parent molecule (1.57 ± 0.03 × 10-5 cm2 s-1). |
| first_indexed | 2024-03-07T02:23:45Z |
| format | Journal article |
| id | oxford-uuid:a4e09ad7-54b7-4a4c-8bd9-c79b96417aeb |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:23:45Z |
| publishDate | 1997 |
| record_format | dspace |
| spelling | oxford-uuid:a4e09ad7-54b7-4a4c-8bd9-c79b96417aeb2022-03-27T02:36:39ZApplications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signalsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a4e09ad7-54b7-4a4c-8bd9-c79b96417aebEnglishSymplectic Elements at Oxford1997Wang, RTam, KMarken, FCompton, RThe use of the channel flow cell for ultraviolet-visible (UV-vis) spectroelectrochemical experiments has been developed to determine the diffusion coefficients of electrogenerated species by means of monitoring the transient absorbance response resulting from a potential step at a working electrode immediately upstream of the incident spectrophotometric beam. The technique is applied to measure the diffusion coefficient of tris(4-bromophenyl)amine (TBPA) radical cation in acetonitrile at 25°C. It is shown that the diffusion coefficient of electrogenerated TBPA radical cation (1.64 ± 0.02 × 10-5 cm-2 s-1) is very close to that of the parent molecule (1.57 ± 0.03 × 10-5 cm2 s-1). |
| spellingShingle | Wang, R Tam, K Marken, F Compton, R Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title | Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title_full | Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title_fullStr | Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title_full_unstemmed | Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title_short | Applications of the channel flow cell for UV-visible spectroelectrochemical studies .2. Transient signals |
| title_sort | applications of the channel flow cell for uv visible spectroelectrochemical studies 2 transient signals |
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