Synthesis of colloidal SU-8 polymer rods using sonication

The bulk synthesis of fluorescent colloidal SU‐8 polymer rods with tunable dimensions is described. The colloidal SU‐8 rods are prepared by shearing an emulsion of SU‐8 polymer droplets and then exposing the resulting non‐Brownian rods to ultrasonic waves, which breaks them into colloidal rods with...

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Main Authors: Fernández-Rico, C, Yanagishima, T, Curran, A, Aarts, D, Dullens, R
Format: Journal article
Published: Wiley 2019
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author Fernández-Rico, C
Yanagishima, T
Curran, A
Aarts, D
Dullens, R
author_facet Fernández-Rico, C
Yanagishima, T
Curran, A
Aarts, D
Dullens, R
author_sort Fernández-Rico, C
collection OXFORD
description The bulk synthesis of fluorescent colloidal SU‐8 polymer rods with tunable dimensions is described. The colloidal SU‐8 rods are prepared by shearing an emulsion of SU‐8 polymer droplets and then exposing the resulting non‐Brownian rods to ultrasonic waves, which breaks them into colloidal rods with typical lengths of 3.5–10 µm and diameters of 0.4–1 µm. The rods are stable in both aqueous and apolar solvents, and by varying the composition of apolar solvent mixtures both the difference in refractive index and mass density between particles and solvent can be independently controlled. Consequently, these colloidal SU‐8 rods can be used in both 3D confocal microscopy and optical trapping experiments while carefully tuning the effect of gravity. This is demonstrated by using confocal microscopy to image the liquid crystalline phases and the isotropic–nematic interface formed by the colloidal SU‐8 rods and by optically trapping single rods in water. Finally, the simultaneous confocal imaging and optical manipulation of multiple SU‐8 rods in the isotropic phase is shown.
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spelling oxford-uuid:a564c678-854b-472b-8568-13667e8134f92022-03-27T02:40:14ZSynthesis of colloidal SU-8 polymer rods using sonicationJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a564c678-854b-472b-8568-13667e8134f9Symplectic Elements at OxfordWiley2019Fernández-Rico, CYanagishima, TCurran, AAarts, DDullens, RThe bulk synthesis of fluorescent colloidal SU‐8 polymer rods with tunable dimensions is described. The colloidal SU‐8 rods are prepared by shearing an emulsion of SU‐8 polymer droplets and then exposing the resulting non‐Brownian rods to ultrasonic waves, which breaks them into colloidal rods with typical lengths of 3.5–10 µm and diameters of 0.4–1 µm. The rods are stable in both aqueous and apolar solvents, and by varying the composition of apolar solvent mixtures both the difference in refractive index and mass density between particles and solvent can be independently controlled. Consequently, these colloidal SU‐8 rods can be used in both 3D confocal microscopy and optical trapping experiments while carefully tuning the effect of gravity. This is demonstrated by using confocal microscopy to image the liquid crystalline phases and the isotropic–nematic interface formed by the colloidal SU‐8 rods and by optically trapping single rods in water. Finally, the simultaneous confocal imaging and optical manipulation of multiple SU‐8 rods in the isotropic phase is shown.
spellingShingle Fernández-Rico, C
Yanagishima, T
Curran, A
Aarts, D
Dullens, R
Synthesis of colloidal SU-8 polymer rods using sonication
title Synthesis of colloidal SU-8 polymer rods using sonication
title_full Synthesis of colloidal SU-8 polymer rods using sonication
title_fullStr Synthesis of colloidal SU-8 polymer rods using sonication
title_full_unstemmed Synthesis of colloidal SU-8 polymer rods using sonication
title_short Synthesis of colloidal SU-8 polymer rods using sonication
title_sort synthesis of colloidal su 8 polymer rods using sonication
work_keys_str_mv AT fernandezricoc synthesisofcolloidalsu8polymerrodsusingsonication
AT yanagishimat synthesisofcolloidalsu8polymerrodsusingsonication
AT currana synthesisofcolloidalsu8polymerrodsusingsonication
AT aartsd synthesisofcolloidalsu8polymerrodsusingsonication
AT dullensr synthesisofcolloidalsu8polymerrodsusingsonication