Rhodium-catalysed enantio- and diastereoselective C(sp2)-C(sp3) cross-coupling reactions

Rhodium-catalysed enantio- and diastereoselective C(sp2)-C(sp3) cross-coupling reactions

<p>In this thesis, we describe a series of Rhodium-catalysed enantio- and diastereoselective C(sp2)–C(sp3) cross-coupling reactions and perform brief mechanistic studies in order to understand their underlying mechanisms.</p> <p>In Chapter 1, cross-coupling reactions are introduce...

Full beskrivning

Bibliografiska uppgifter
Huvudupphovsman:	Goetzke, FW
Övriga upphovsmän:	Fletcher, SP
Materialtyp:	Lärdomsprov
Språk:	English
Publicerad:	2021

Liknande verk

Enantio- and diastereoselective Suzuki-Miyaura coupling with racemic bicycles
av: Goetzke, F, et al.
Publicerad: (2019)

Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades.
av: Li, M, et al.
Publicerad: (2013)

Enantio- and diastereoselective catalytic alkylation reactions with aziridines.
av: Moss, T, et al.
Publicerad: (2008)

Rhodium-catalysed C(sp2)–C(sp2) bond formation via C–H/C–F activation
av: Tian, Panpan, et al.
Publicerad: (2018)

Direct catalytic enantio- and diastereoselective Mannich reaction of isocyanoacetates and ketimines.
av: Ortín, I, et al.
Publicerad: (2014)

The understanding and development of rhodium-catalysed asymmetric cross-coupling reactions
av: Van Dijk, L
Publicerad: (2021)

Catalytic enantio- and diastereoselective Mannich reaction of α-substituted isocyanoacetates and ketimines.
av: de la Campa, R, et al.
Publicerad: (2016)

Catalytic enantio- and diastereoselective alkylations with cyclic sulfamidates.
av: Moss, T, et al.
Publicerad: (2010)

Rhodium-catalysed regio- and enantioselective Suzuki-Miyaura cross-coupling reactions
av: Liu, K
Publicerad: (2023)

Bifunctional iminophosphorane superbases: Potent organocatalysts for enantio- and diastereoselective Michael addition reactions
av: Farley, A, et al.
Publicerad: (2018)

Cobalt‐catalyzed enantio‐ and regioselective C(sp3)−H alkenylation of thioamides
av: Staronova, L, et al.
Publicerad: (2024)

Enantio and Diastereoselective Addition of Phenylacetylene to Racemic α-chloroketones
av: Pier Giorgio Cozzi, et al.
Publicerad: (2011-06-01)

Direct enantio- and diastereoselective Mannich reactions of malonate and beta-keto esters with N-Boc and N-Cbz aldimines catalysed by a bifunctional cinchonine derivative.
av: Tillman, A, et al.
Publicerad: (2006)

Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization.
av: Straker, R, et al.
Publicerad: (2016)

Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization
av: R. N. Straker, et al.
Publicerad: (2016-01-01)

Catalytic enantio- and diastereoselective mannich addition of TosMIC to ketimines
av: Franchino, A, et al.
Publicerad: (2018)

A rhodium-catalysed Sonogashira-type coupling exploiting C–S functionalisation: orthogonality with palladium-catalysed variants
av: Arambasic, M, et al.
Publicerad: (2019)

Multimetallic catalysed radical oxidative C(sp3)–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
av: Shan Tang, et al.
Publicerad: (2016-06-01)

Highly enantio- and diastereoselective reactions of γ-substituted butenolides through direct vinylogous conjugate additions
av: Zhang, Wen, et al.
Publicerad: (2013)

Rhodium catalysed hydroacylation reactions in the synthesis of heterocycles
av: Ylioja, P
Publicerad: (2011)

Enantio- and diastereoselective Michael additions of C-succinimidyl esters to nitro olefins using cinchonine-derived bifunctional organocatalysts
av: Jakubec, P, et al.
Publicerad: (2011)

Nickel-Catalyzed Enantio- and Diastereoselective Synthesis of Fluorine-Containing Vicinal Stereogenic Centers
av: Uttam Dhawa, et al.
Publicerad: (2024-08-01)

Organocatalytic enantio- and diastereoselective cycloetherification via dynamic kinetic resolution of chiral cyanohydrins
av: Naoki Yoneda, et al.
Publicerad: (2017-11-01)

Controlling selectivity in the rhodium-catalysed intermolecular hydroacylation reaction
av: Pawley, R
Publicerad: (2012)

Exploring and exploiting selectivity in Rhodium-catalysed hydroacylation reactions
av: Poingdestre, SJ
Publicerad: (2012)

Rhodium catalysed C-3/5 methylation of pyridines using temporary dearomatisation
av: Grosavu, A, et al.
Publicerad: (2020)

Combining cycloisomerization with trienamine catalysis: a regiochemically flexible enantio- and diastereoselective synthesis of hexahydroindoles
av: Chintalapudi, V, et al.
Publicerad: (2015)

Novel Chiral Thiourea Derived from Hydroquinine and l‑Phenylglycinol: An Effective Catalyst for Enantio- and Diastereoselective Aza-Henry Reaction
av: Jingdong Wang, et al.
Publicerad: (2021-02-01)

Development and applications of rhodium-catalysed reactions to explore the synthesis of heterocycles
av: Niu, J
Publicerad: (2016)

Studies toward the application and development of rhodium-catalysed hydroacylation reactions
av: Neuhaus, J
Publicerad: (2016)

Intramolecular cascade annulation triggered by rhodium(III)-catalyzed sequential C(sp2)–H activation and C(sp3)–H amination
av: Liangliang Song, et al.
Publicerad: (2019-02-01)

Copper-catalyzed C(sp)-C(sp2) oxidative cross coupling reaction to access to methyl arylpropiolates at room temperature
av: Jinghong Min, et al.
Publicerad: (2021-11-01)

Transition metal-catalysed A-ring C–H activations and C(sp2)–C(sp2) couplings in the 13α-oestrone series and in vitro evaluation of antiproliferative properties
av: Péter Traj, et al.
Publicerad: (2021-01-01)

Enantio- and diastereoselective synthesis of chromeno[4,3-b]pyrrole derivatives bearing tetrasubstituted chirality centers through carbene catalyzed cascade reactions
av: Li, Tingting, et al.
Publicerad: (2020)

Carbon-carbon bond formation via rhodium-catalysed C-S activation processes
av: Arambasic, M
Publicerad: (2015)

Cp*Rh(III)-catalysed enantioselective C(sp3)–H functionalisation
av: Xu, X
Publicerad: (2024)

New applications of rhodium-catalysed hydroacylation
av: Iwumene, NUN
Publicerad: (2022)

Highly chemo-, enantio-, and diastereoselective [4 + 2] cycloaddition of 5H-thiazol-4-ones with N-itaconimides
av: Shuai Qiu, et al.
Publicerad: (2016-11-01)

Rhodium(II)-catalyzed multicomponent assembly of α,α,α-trisubstituted esters via formal insertion of O–C(sp3)–C(sp2) into C–C bonds
av: Dan Ba, et al.
Publicerad: (2020-08-01)

Organocatalytic asymmetric Mannich reactions of 5H-oxazol-4-ones : highly enantio- and diastereoselective synthesis of chiral α-alkylisoserine derivatives
av: Han, Zhiqiang, et al.
Publicerad: (2014)