STEREOSELECTIVE DIELS-ALDER REACTIONS OF A NEW CHIRAL CARBAMOYLNITROSO COMPOUND
A new chiral carbamoylnitroso dienophile 1 has been prepared from a substituted pyrrolidine possessing C2 symmetry. Compound 1 reacts with dienes to yield (4 + 2) cycloadducts with very high diastereoisomeric excesses. © 1990.
Main Authors: | , |
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Format: | Journal article |
Language: | English |
Published: |
1990
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Summary: | A new chiral carbamoylnitroso dienophile 1 has been prepared from a substituted pyrrolidine possessing C2 symmetry. Compound 1 reacts with dienes to yield (4 + 2) cycloadducts with very high diastereoisomeric excesses. © 1990. |
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