Re(I) sensitised near-infrared lanthanide luminescence from a hetero-trinuclear Re2Ln array.
The trinuclear complexes Re2Ln (Ln = Nd, Yb or Er) contain two Re(I) tricarbonyl units linked to a DTPA binding site via 2,2'-bipyridyl ligands; Ln(III)-centred emission is sensitised by the Re(I) MLCT excited states.
| Autors principals: | , , |
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| Format: | Journal article |
| Idioma: | English |
| Publicat: |
2004
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| Sumari: | The trinuclear complexes Re2Ln (Ln = Nd, Yb or Er) contain two Re(I) tricarbonyl units linked to a DTPA binding site via 2,2'-bipyridyl ligands; Ln(III)-centred emission is sensitised by the Re(I) MLCT excited states. |
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