Single and double stereoselective fluorination of (E)-allylsilanes.

Single and double stereoselective fluorination of (E)-allylsilanes.

Veure altres versions (1)

Acyclic allylic monofluorides were prepared by electrophilic fluorination of branched (E)-allylsilanes with Selectfluor. These reactions proceeded with efficient transfer of chirality from the silylated to the fluorinated stereocentre. Upon double fluorination, an unsymmetrical ethyl syn-2,5-difluor...

Descripció completa

Dades bibliogràfiques
Autors principals:	Sawicki, M, Kwok, A, Tredwell, M, Gouverneur, V
Format:	Journal article
Idioma:	English
Publicat:	2007

Ítems similars

Single and double stereoselective fluorination of (E)-allylsilanes
per: Sawicki, M, et al.
Publicat: (2007)

ORGN 257-Electrophilic fluorination of acyclic chiral allylsilanes
per: Tredwell, M, et al.
Publicat: (2006)

Synthesis of novel enantiopure fluorinated building blocks from acyclic chiral allylsilanes.
per: Tredwell, M, et al.
Publicat: (2005)

ORGN 439-Diastereoselective electrophilic fluorination of chiral allylsilanes
per: Purser, S, et al.
Publicat: (2007)

Stereoselective synthesis of fluorinated pyrrolidines
per: Combettes, L, et al.
Publicat: (2010)

Electrophilic fluorination of organosilanes.
per: Tredwell, M, et al.
Publicat: (2006)

1.5 Fluorine in Medicinal Chemistry: Importance of Chirality
per: Tredwell, M, et al.
Publicat: (2012)

Trifluoromethylation of allylsilanes under copper catalysis.
per: Mizuta, S, et al.
Publicat: (2012)

Trifluoromethylation of allylsilanes under photoredox catalysis.
per: Mizuta, S, et al.
Publicat: (2013)

Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines
per: Combettes, L, et al.
Publicat: (2012)

Metal free fluoroamination of allylsilanes: A route to 3-fluoropyrrolidines
per: Combettes, L, et al.
Publicat: (2012)

Electrophilic fluorodesilylation of allylsilanes: A mild synthetic route to allylic fluorides.
per: Greedy, B, et al.
Publicat: (2002)

Synthesis and trifluoromethylation of allylsilanes
per: Galicia Lopez, O
Publicat: (2013)

Photoredox Nucleophilic (Radio)fluorination of Alkoxyamines
per: Ortalli, S, et al.
Publicat: (2024)

Fluorine-directed diastereoselective iodocyclizations.
per: Tredwell, M, et al.
Publicat: (2008)

A convergent approach for the synthesis of fluorinated sphingosine analogues
per: Teare, H, et al.
Publicat: (2007)

Palladium-catalyzed allylic fluorination.
per: Hollingworth, C, et al.
Publicat: (2011)

Asymmetric de novo synthesis of fluorinated D-glucitol and D-mannitol analogues
per: Giuffredi, G, et al.
Publicat: (2009)

In My Element: Fluorine
per: Gouverneur, V
Publicat: (2019)

Molecular editing with fluorine
per: Gouverneur, V
Publicat: (2011)

Gold Catalysis and Fluorine
per: Hopkinson, M, et al.
Publicat: (2010)

Asymmetric de novo synthesis of fluorinated L-glucitol and L-mannitol analogues (vol 20, pg 910, 2009)
per: Giuffredi, G, et al.
Publicat: (2010)

Transition metal catalyzed fluorination
per: Gouverneur, V
Publicat: (2012)

Catalytic asymmetric fluorinations.
per: Bobbio, C, et al.
Publicat: (2006)

Sequential desymmetrization-fluorination: enantioselective synthesis of fluorinated cyclitols.
per: Purser, S, et al.
Publicat: (2006)

A general copper-mediated nucleophilic 18F fluorination of arenes.
per: Tredwell, M, et al.
Publicat: (2014)

A general copper-mediated nucleophilic 18F fluorination of arenes
per: Tredwell, M, et al.
Publicat: (2014)

Fluorine in medicinal chemistry.
per: Purser, S, et al.
Publicat: (2008)

Diastereoselective fluorination of silylated 1,2-oxazines to access fluorinated N,O-heterocycles
per: Lam, Y, et al.
Publicat: (2007)

Metal-free oxidative fluorination of phenols with [18F]fluoride.
per: Gao, Z, et al.
Publicat: (2012)

Chemistry. A new departure in fluorination chemistry.
per: Gouverneur, V
Publicat: (2009)

Stereoselective synthesis of internal allylic fluorides.
per: Thibaudeau, S, et al.
Publicat: (2004)

Derisking the Cu-mediated (18)F-fluorination of heterocyclic positron emission tomography radioligands
per: Taylor, N, et al.
Publicat: (2017)

Palladium catalyzed allylic fluorination
per: Hollingworth, C, et al.
Publicat: (2012)

Transition metal catalysis and nucleophilic fluorination.
per: Hollingworth, C, et al.
Publicat: (2012)

Corrigendum to "Asymmetric de novo synthesis of fluorinated l-glucitol and l-mannitol analogues" [Tetrahedron: Asymmetry 20 (2009) 910] (DOI:10.1016/j.tetasy.2009.03.001)
per: Giuffredi, G, et al.
Publicat: (2010)

Catalytic decarboxylative fluorination for the synthesis of tri- and difluoromethyl arenes.
per: Mizuta, S, et al.
Publicat: (2013)

FLUO 3-Novel approaches for the synthesis of fluorinated heterocycles
per: Gouverneur, V
Publicat: (2008)

Silylated allenes as precursors of fluorinated dienes and propargylic fluorides
per: Pacheco, M, et al.
Publicat: (2005)

STEREOSELECTIVE DIELS-ALDER REACTIONS OF A NEW CHIRAL CARBAMOYLNITROSO COMPOUND
per: Gouverneur, V, et al.
Publicat: (1990)