Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.

A novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuni...

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Main Authors: Lawrence, K, Xia, F, Arrowsmith, R, Ge, H, Nelson, G, Foord, J, Felipe-Sotelo, M, Evans, N, Mitchels, J, Flower, SE, Botchway, S, Wolverson, D, Aliev, G, James, T, Pascu, S, Marken, F
Format: Journal article
Language:English
Published: American Chemical Society 2014
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author Lawrence, K
Xia, F
Arrowsmith, R
Ge, H
Nelson, G
Foord, J
Felipe-Sotelo, M
Evans, N
Mitchels, J
Flower, SE
Botchway, S
Wolverson, D
Aliev, G
James, T
Pascu, S
Marken, F
author_facet Lawrence, K
Xia, F
Arrowsmith, R
Ge, H
Nelson, G
Foord, J
Felipe-Sotelo, M
Evans, N
Mitchels, J
Flower, SE
Botchway, S
Wolverson, D
Aliev, G
James, T
Pascu, S
Marken, F
author_sort Lawrence, K
collection OXFORD
description A novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuniform particle diameter (ranging from sub-6 to 20 nm with some aggregates up to 200 nm) exhibit strong fluorescence properties in different solvents and have also been investigated for applications in cell culture media. The cP4VP dots retain their intrinsic fluorescence in a cellular environment and exhibit an average excited-state lifetime of 2.0 ± 0.9 ns in the cell. The cP4VP dots enter HeLa cells and do not cause significant damage to outer cell membranes. They provide one-photon or two-photon fluorescent synthetic scaffolds for imaging applications and/or drug delivery.
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spelling oxford-uuid:a621b535-0b3b-4793-9977-0c5dcac7bb942022-03-27T02:45:10ZHydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a621b535-0b3b-4793-9977-0c5dcac7bb94EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Lawrence, KXia, FArrowsmith, RGe, HNelson, GFoord, JFelipe-Sotelo, MEvans, NMitchels, JFlower, SEBotchway, SWolverson, DAliev, GJames, TPascu, SMarken, FA novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuniform particle diameter (ranging from sub-6 to 20 nm with some aggregates up to 200 nm) exhibit strong fluorescence properties in different solvents and have also been investigated for applications in cell culture media. The cP4VP dots retain their intrinsic fluorescence in a cellular environment and exhibit an average excited-state lifetime of 2.0 ± 0.9 ns in the cell. The cP4VP dots enter HeLa cells and do not cause significant damage to outer cell membranes. They provide one-photon or two-photon fluorescent synthetic scaffolds for imaging applications and/or drug delivery.
spellingShingle Lawrence, K
Xia, F
Arrowsmith, R
Ge, H
Nelson, G
Foord, J
Felipe-Sotelo, M
Evans, N
Mitchels, J
Flower, SE
Botchway, S
Wolverson, D
Aliev, G
James, T
Pascu, S
Marken, F
Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title_full Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title_fullStr Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title_full_unstemmed Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title_short Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
title_sort hydrothermal conversion of one photon fluorescent poly 4 vinylpyridine into two photon fluorescent carbon nanodots
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