Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.
A novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuni...
Main Authors: | , , , , , , , , , , , , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
American Chemical Society
2014
|
_version_ | 1797086831411462144 |
---|---|
author | Lawrence, K Xia, F Arrowsmith, R Ge, H Nelson, G Foord, J Felipe-Sotelo, M Evans, N Mitchels, J Flower, SE Botchway, S Wolverson, D Aliev, G James, T Pascu, S Marken, F |
author_facet | Lawrence, K Xia, F Arrowsmith, R Ge, H Nelson, G Foord, J Felipe-Sotelo, M Evans, N Mitchels, J Flower, SE Botchway, S Wolverson, D Aliev, G James, T Pascu, S Marken, F |
author_sort | Lawrence, K |
collection | OXFORD |
description | A novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuniform particle diameter (ranging from sub-6 to 20 nm with some aggregates up to 200 nm) exhibit strong fluorescence properties in different solvents and have also been investigated for applications in cell culture media. The cP4VP dots retain their intrinsic fluorescence in a cellular environment and exhibit an average excited-state lifetime of 2.0 ± 0.9 ns in the cell. The cP4VP dots enter HeLa cells and do not cause significant damage to outer cell membranes. They provide one-photon or two-photon fluorescent synthetic scaffolds for imaging applications and/or drug delivery. |
first_indexed | 2024-03-07T02:27:33Z |
format | Journal article |
id | oxford-uuid:a621b535-0b3b-4793-9977-0c5dcac7bb94 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:27:33Z |
publishDate | 2014 |
publisher | American Chemical Society |
record_format | dspace |
spelling | oxford-uuid:a621b535-0b3b-4793-9977-0c5dcac7bb942022-03-27T02:45:10ZHydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a621b535-0b3b-4793-9977-0c5dcac7bb94EnglishSymplectic Elements at OxfordAmerican Chemical Society2014Lawrence, KXia, FArrowsmith, RGe, HNelson, GFoord, JFelipe-Sotelo, MEvans, NMitchels, JFlower, SEBotchway, SWolverson, DAliev, GJames, TPascu, SMarken, FA novel two-photon-fluorescent N,O-heteroatom-rich carbon nanomaterial has been synthesized and characterized. The new carbon nanoparticles were produced by hydrothermal conversion from a one-photon-fluorescent poly(4-vinylpyridine) precursor (P4VP). The carbonized particles (cP4VP dots) with nonuniform particle diameter (ranging from sub-6 to 20 nm with some aggregates up to 200 nm) exhibit strong fluorescence properties in different solvents and have also been investigated for applications in cell culture media. The cP4VP dots retain their intrinsic fluorescence in a cellular environment and exhibit an average excited-state lifetime of 2.0 ± 0.9 ns in the cell. The cP4VP dots enter HeLa cells and do not cause significant damage to outer cell membranes. They provide one-photon or two-photon fluorescent synthetic scaffolds for imaging applications and/or drug delivery. |
spellingShingle | Lawrence, K Xia, F Arrowsmith, R Ge, H Nelson, G Foord, J Felipe-Sotelo, M Evans, N Mitchels, J Flower, SE Botchway, S Wolverson, D Aliev, G James, T Pascu, S Marken, F Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title | Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title_full | Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title_fullStr | Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title_full_unstemmed | Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title_short | Hydrothermal conversion of one-photon-fluorescent poly(4-vinylpyridine) into two-photon-fluorescent carbon nanodots. |
title_sort | hydrothermal conversion of one photon fluorescent poly 4 vinylpyridine into two photon fluorescent carbon nanodots |
work_keys_str_mv | AT lawrencek hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT xiaf hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT arrowsmithr hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT geh hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT nelsong hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT foordj hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT felipesotelom hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT evansn hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT mitchelsj hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT flowerse hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT botchways hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT wolversond hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT alievg hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT jamest hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT pascus hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots AT markenf hydrothermalconversionofonephotonfluorescentpoly4vinylpyridineintotwophotonfluorescentcarbonnanodots |