Catalytic stereoselective semihydrogenation of alkynes to E-alkenes.

Less is more: Significant advancements have been made in recent years in the development of the E-selective, catalytic, functional-group-tolerant semihydrogenation of alkynes to E-alkenes through transition-metal catalysis (see scheme). For this type of catalysis, the use of mononuclear metal cataly...

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Bibliographic Details
Main Authors: Michaelides, I, Dixon, D
Format: Journal article
Language:English
Published: 2013
Description
Summary:Less is more: Significant advancements have been made in recent years in the development of the E-selective, catalytic, functional-group-tolerant semihydrogenation of alkynes to E-alkenes through transition-metal catalysis (see scheme). For this type of catalysis, the use of mononuclear metal catalysts is superior to that of multinuclear metal catalysts. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim.