Microwave activation of electrochemical processes at microelectrodes
Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a...
| Main Authors: | , , |
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| Format: | Journal article |
| Sprog: | English |
| Udgivet: |
1998
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| Summary: | Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a rapid heating effect causing the temperature in the liquid phase at the electrode/solution interface to locally superheat. |
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