Microwave activation of electrochemical processes at microelectrodes
Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a...
主要な著者: | , , |
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フォーマット: | Journal article |
言語: | English |
出版事項: |
1998
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_version_ | 1826289466205011968 |
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author | Compton, R Coles, B Marken, F |
author_facet | Compton, R Coles, B Marken, F |
author_sort | Compton, R |
collection | OXFORD |
description | Electrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a rapid heating effect causing the temperature in the liquid phase at the electrode/solution interface to locally superheat. |
first_indexed | 2024-03-07T02:29:18Z |
format | Journal article |
id | oxford-uuid:a6b17427-a465-44ad-9e57-48cf39b51cbe |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T02:29:18Z |
publishDate | 1998 |
record_format | dspace |
spelling | oxford-uuid:a6b17427-a465-44ad-9e57-48cf39b51cbe2022-03-27T02:49:02ZMicrowave activation of electrochemical processes at microelectrodesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a6b17427-a465-44ad-9e57-48cf39b51cbeEnglishSymplectic Elements at Oxford1998Compton, RColes, BMarken, FElectrochemical experiments at platinum microdisc electrodes are shown to be possible in an environment of intense microwave radiation and a considerable current enhancement observed for the ferrocyanide/ferricyanide redox couple in aqueous 1 M KCl is shown to be Faradaic in nature consistent with a rapid heating effect causing the temperature in the liquid phase at the electrode/solution interface to locally superheat. |
spellingShingle | Compton, R Coles, B Marken, F Microwave activation of electrochemical processes at microelectrodes |
title | Microwave activation of electrochemical processes at microelectrodes |
title_full | Microwave activation of electrochemical processes at microelectrodes |
title_fullStr | Microwave activation of electrochemical processes at microelectrodes |
title_full_unstemmed | Microwave activation of electrochemical processes at microelectrodes |
title_short | Microwave activation of electrochemical processes at microelectrodes |
title_sort | microwave activation of electrochemical processes at microelectrodes |
work_keys_str_mv | AT comptonr microwaveactivationofelectrochemicalprocessesatmicroelectrodes AT colesb microwaveactivationofelectrochemicalprocessesatmicroelectrodes AT markenf microwaveactivationofelectrochemicalprocessesatmicroelectrodes |