When does near-wall hindered diffusion influence mass transport towards targets?

The diffusion of a particle is slowed as it moves close to a surface. We identify the conditions under which this hindered diffusion is significant and show that is strongly dependant on the sizes of both the particle and the target. We focus particularly on the transport of nano-particles to a vari...

Полное описание

Библиографические подробности
Главные авторы: Eloul, S, Kätelhön, E, Compton, R
Формат: Journal article
Язык:English
Опубликовано: Royal Society of Chemistry 2016
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author Eloul, S
Kätelhön, E
Compton, R
author_facet Eloul, S
Kätelhön, E
Compton, R
author_sort Eloul, S
collection OXFORD
description The diffusion of a particle is slowed as it moves close to a surface. We identify the conditions under which this hindered diffusion is significant and show that is strongly dependant on the sizes of both the particle and the target. We focus particularly on the transport of nano-particles to a variety of targets including a planar surface, a sphere, a disc and a wire, and provide data which allows the frequency of impacts to be inferred for a variety of experimental conditions. Equations are given to estimate the particle fluxes and we explain literature observations reported on the detected frequency of impacts. Finally we observe a drastic effect on the calculation of the mean first passage time of a single particle impacting a sub-micron sized target, showing the importance of this effect in biological systems.
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spelling oxford-uuid:a7c587d3-b44c-4cfd-8ab7-6d9a5e0a46b32022-03-27T02:56:46ZWhen does near-wall hindered diffusion influence mass transport towards targets?Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a7c587d3-b44c-4cfd-8ab7-6d9a5e0a46b3EnglishSymplectic Elements at OxfordRoyal Society of Chemistry2016Eloul, SKätelhön, ECompton, RThe diffusion of a particle is slowed as it moves close to a surface. We identify the conditions under which this hindered diffusion is significant and show that is strongly dependant on the sizes of both the particle and the target. We focus particularly on the transport of nano-particles to a variety of targets including a planar surface, a sphere, a disc and a wire, and provide data which allows the frequency of impacts to be inferred for a variety of experimental conditions. Equations are given to estimate the particle fluxes and we explain literature observations reported on the detected frequency of impacts. Finally we observe a drastic effect on the calculation of the mean first passage time of a single particle impacting a sub-micron sized target, showing the importance of this effect in biological systems.
spellingShingle Eloul, S
Kätelhön, E
Compton, R
When does near-wall hindered diffusion influence mass transport towards targets?
title When does near-wall hindered diffusion influence mass transport towards targets?
title_full When does near-wall hindered diffusion influence mass transport towards targets?
title_fullStr When does near-wall hindered diffusion influence mass transport towards targets?
title_full_unstemmed When does near-wall hindered diffusion influence mass transport towards targets?
title_short When does near-wall hindered diffusion influence mass transport towards targets?
title_sort when does near wall hindered diffusion influence mass transport towards targets
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AT katelhone whendoesnearwallhindereddiffusioninfluencemasstransporttowardstargets
AT comptonr whendoesnearwallhindereddiffusioninfluencemasstransporttowardstargets