Electronic coupling in mixed-valence dinuclear ferrocenes and cobaltocenes with saturated bridging groups.
We have synthesised a series of new dinuclear metallocenes [{M(Cp*)(C5H4)}2X] (Cp* = eta5-pentamethylcyclopentadienyl; M = Fe, Co, X = CMe2, SiMe2, GeMe2; M = Fe, X = Si2Me4). For the neutral dicobalt complexes, magnetic susceptibility measurements reveal intramolecular antiferromagnetic interaction...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2005
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