Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.
The first Group 4 alkoxyimido compounds are reported. The Ti=N-O(t)Bu group in Ti(N(2)N(Me))(NO(t)Bu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2011
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| _version_ | 1797087320362450944 |
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| author | Schwarz, A Nova, A Clot, E Mountford, P |
| author_facet | Schwarz, A Nova, A Clot, E Mountford, P |
| author_sort | Schwarz, A |
| collection | OXFORD |
| description | The first Group 4 alkoxyimido compounds are reported. The Ti=N-O(t)Bu group in Ti(N(2)N(Me))(NO(t)Bu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events. |
| first_indexed | 2024-03-07T02:34:07Z |
| format | Journal article |
| id | oxford-uuid:a8366bfb-b830-4665-bac6-a5fe3dce0ce2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:34:07Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:a8366bfb-b830-4665-bac6-a5fe3dce0ce22022-03-27T02:59:51ZTitanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a8366bfb-b830-4665-bac6-a5fe3dce0ce2EnglishSymplectic Elements at Oxford2011Schwarz, ANova, AClot, EMountford, PThe first Group 4 alkoxyimido compounds are reported. The Ti=N-O(t)Bu group in Ti(N(2)N(Me))(NO(t)Bu)(py) undergoes facile 2-electron N-O bond cleavage with PhCCMe as the reductant to form a 1,2-diamidoalkene group via two highly selective N-C bond forming events. |
| spellingShingle | Schwarz, A Nova, A Clot, E Mountford, P Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title | Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title_full | Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title_fullStr | Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title_full_unstemmed | Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title_short | Titanium alkoxyimido (Ti=N-OR) complexes: reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands. |
| title_sort | titanium alkoxyimido ti n or complexes reductive n o bond cleavage at the boundary between hydrazide and peroxide ligands |
| work_keys_str_mv | AT schwarza titaniumalkoxyimidotinorcomplexesreductivenobondcleavageattheboundarybetweenhydrazideandperoxideligands AT novaa titaniumalkoxyimidotinorcomplexesreductivenobondcleavageattheboundarybetweenhydrazideandperoxideligands AT clote titaniumalkoxyimidotinorcomplexesreductivenobondcleavageattheboundarybetweenhydrazideandperoxideligands AT mountfordp titaniumalkoxyimidotinorcomplexesreductivenobondcleavageattheboundarybetweenhydrazideandperoxideligands |