Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles.
We report the electrocatalytic dehalogenation of trichloroethylene by single soft nanoparticles of VB12 containing droplets, and find that the binding between Co (I), the reduced form of Co (III), and TCE is likely a chemically reversible process and in particular using this model system quantify th...
| Main Authors: | , |
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| Format: | Journal article |
| Language: | English |
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Wiley
2016
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| _version_ | 1797087349582069760 |
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| author | Cheng, W Compton, R |
| author_facet | Cheng, W Compton, R |
| author_sort | Cheng, W |
| collection | OXFORD |
| description | We report the electrocatalytic dehalogenation of trichloroethylene by single soft nanoparticles of VB12 containing droplets, and find that the binding between Co (I), the reduced form of Co (III), and TCE is likely a chemically reversible process and in particular using this model system quantify the turnover number and the kinetics of catalytic reactions at individual single soft nanoparticles in real time. |
| first_indexed | 2024-03-07T02:34:30Z |
| format | Journal article |
| id | oxford-uuid:a855cbef-de6d-4dfd-9a71-730395e68f9a |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:34:30Z |
| publishDate | 2016 |
| publisher | Wiley |
| record_format | dspace |
| spelling | oxford-uuid:a855cbef-de6d-4dfd-9a71-730395e68f9a2022-03-27T03:00:47ZQuantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a855cbef-de6d-4dfd-9a71-730395e68f9aEnglishSymplectic Elements at OxfordWiley2016Cheng, WCompton, RWe report the electrocatalytic dehalogenation of trichloroethylene by single soft nanoparticles of VB12 containing droplets, and find that the binding between Co (I), the reduced form of Co (III), and TCE is likely a chemically reversible process and in particular using this model system quantify the turnover number and the kinetics of catalytic reactions at individual single soft nanoparticles in real time. |
| spellingShingle | Cheng, W Compton, R Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title | Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title_full | Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title_fullStr | Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title_full_unstemmed | Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title_short | Quantifying the electrocatalytic turnover of vitamin B12-mediated dehalogenation on single soft nanoparticles. |
| title_sort | quantifying the electrocatalytic turnover of vitamin b12 mediated dehalogenation on single soft nanoparticles |
| work_keys_str_mv | AT chengw quantifyingtheelectrocatalyticturnoverofvitaminb12mediateddehalogenationonsinglesoftnanoparticles AT comptonr quantifyingtheelectrocatalyticturnoverofvitaminb12mediateddehalogenationonsinglesoftnanoparticles |