Sono-emulsion electrosynthesis: electrode-insensitive Kolbe reactions
The electro-oxidation of water-immiscible liquid aliphatic acids (RCO2H) leading to decarboxylation to afford a hyrocarbon (R-R) may be achieved using an emulsion formed via insonation so that the organic phase continuously extracts the products; in complete contrast to conventional monophasic elect...
| Główni autorzy: | , , , , |
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| Format: | Journal article |
| Język: | English |
| Wydane: |
2001
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| Streszczenie: | The electro-oxidation of water-immiscible liquid aliphatic acids (RCO2H) leading to decarboxylation to afford a hyrocarbon (R-R) may be achieved using an emulsion formed via insonation so that the organic phase continuously extracts the products; in complete contrast to conventional monophasic electrolyses, the type and yield of products obtained from this biphasic Kolbe electrolysis are independent of the electrode material used. |
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