Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.
A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2006
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| _version_ | 1826289887264899072 |
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| author | Paddon, C Bhatti, F Donohoe, T Compton, R |
| author_facet | Paddon, C Bhatti, F Donohoe, T Compton, R |
| author_sort | Paddon, C |
| collection | OXFORD |
| description | A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions. |
| first_indexed | 2024-03-07T02:35:45Z |
| format | Journal article |
| id | oxford-uuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc6 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T02:35:45Z |
| publishDate | 2006 |
| record_format | dspace |
| spelling | oxford-uuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc62022-03-27T03:03:36ZCryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a8bbefd4-75d3-4d40-b9fb-fa8447870dc6EnglishSymplectic Elements at Oxford2006Paddon, CBhatti, FDonohoe, TCompton, RA series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions. |
| spellingShingle | Paddon, C Bhatti, F Donohoe, T Compton, R Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title | Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title_full | Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title_fullStr | Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title_full_unstemmed | Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title_short | Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable. |
| title_sort | cryovoltammetrically probing functional group reductive cleavage alkyl sulfur versus aryl sulfur bond cleavage in an alkyl naphthyl thioether under single electron transfer is temperature switchable |
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