Cryovoltammetrically probing functional group reductive cleavage: alkyl-sulfur versus aryl-sulfur bond cleavage in an alkyl naphthyl thioether under single electron-transfer is temperature switchable.
A series of single electron-transfer (SET) reactions on a naphthyl thioether have shown that the reductive cleavage mechanism changes at low temperatures and this selectivity is proved using an electrochemical analysis that mimics the SET reaction conditions.
Auteurs principaux: | Paddon, C, Bhatti, F, Donohoe, T, Compton, R |
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Format: | Journal article |
Langue: | English |
Publié: |
2006
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