A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+
Owing to its high toxicity, the chemistry of element number four, beryllium, is poorly understood. However, as the lightest elements provide the basis for fundamental models of chemical bonding, there is a need for greater insight into the properties of beryllium. In this context, the chemistry of t...
| Autori principali: | , , , |
|---|---|
| Natura: | Journal article |
| Lingua: | English |
| Pubblicazione: |
Nature Research
2024
|
| _version_ | 1826313812066697216 |
|---|---|
| author | Boronski, JT Crumpton, AE Roper, AF Aldridge, S |
| author_facet | Boronski, JT Crumpton, AE Roper, AF Aldridge, S |
| author_sort | Boronski, JT |
| collection | OXFORD |
| description | Owing to its high toxicity, the chemistry of element number four, beryllium, is poorly understood. However, as the lightest elements provide the basis for fundamental models of chemical bonding, there is a need for greater insight into the properties of beryllium. In this context, the chemistry of the homo-elemental Be–Be bond is of fundamental interest. Here the ligand metathesis chemistry of diberyllocene (1; CpBeBeCp)—a stable complex with a Be–Be bond—has been investigated. These studies yield two complexes with Be–Be bonds: Cp*BeBeCp (2) and [K{(HCDippN)2BO}2]BeBeCp (3; Dipp = 2,6-diisopropylphenyl). Quantum chemical calculations indicate that the Be–Be bond in 3 is polarized to such an extent that the complex could be formulated as a mixed-oxidation state Be0/BeII complex. Correspondingly, it is demonstrated that 3 can transfer the ‘beryllyl’ anion, [BeCp]−, to an organic substrate, by analogy with the reactivity of sp2–sp3 diboranes. Indeed, this work reveals striking similarities between the homo-elemental bonding linkages of beryllium and boron, despite the respective metallic and non-metallic natures of these elements. |
| first_indexed | 2024-09-25T04:22:28Z |
| format | Journal article |
| id | oxford-uuid:a9617d13-0c64-4376-b28a-7b8093e42fd9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-09-25T04:22:28Z |
| publishDate | 2024 |
| publisher | Nature Research |
| record_format | dspace |
| spelling | oxford-uuid:a9617d13-0c64-4376-b28a-7b8093e42fd92024-08-14T20:12:55ZA nucleophilic beryllyl complex via metathesis at [Be–Be] 2+Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:a9617d13-0c64-4376-b28a-7b8093e42fd9EnglishJisc Publications RouterNature Research2024Boronski, JTCrumpton, AERoper, AFAldridge, SOwing to its high toxicity, the chemistry of element number four, beryllium, is poorly understood. However, as the lightest elements provide the basis for fundamental models of chemical bonding, there is a need for greater insight into the properties of beryllium. In this context, the chemistry of the homo-elemental Be–Be bond is of fundamental interest. Here the ligand metathesis chemistry of diberyllocene (1; CpBeBeCp)—a stable complex with a Be–Be bond—has been investigated. These studies yield two complexes with Be–Be bonds: Cp*BeBeCp (2) and [K{(HCDippN)2BO}2]BeBeCp (3; Dipp = 2,6-diisopropylphenyl). Quantum chemical calculations indicate that the Be–Be bond in 3 is polarized to such an extent that the complex could be formulated as a mixed-oxidation state Be0/BeII complex. Correspondingly, it is demonstrated that 3 can transfer the ‘beryllyl’ anion, [BeCp]−, to an organic substrate, by analogy with the reactivity of sp2–sp3 diboranes. Indeed, this work reveals striking similarities between the homo-elemental bonding linkages of beryllium and boron, despite the respective metallic and non-metallic natures of these elements. |
| spellingShingle | Boronski, JT Crumpton, AE Roper, AF Aldridge, S A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title | A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title_full | A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title_fullStr | A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title_full_unstemmed | A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title_short | A nucleophilic beryllyl complex via metathesis at [Be–Be] 2+ |
| title_sort | nucleophilic beryllyl complex via metathesis at be be 2 |
| work_keys_str_mv | AT boronskijt anucleophilicberyllylcomplexviametathesisatbebe2 AT crumptonae anucleophilicberyllylcomplexviametathesisatbebe2 AT roperaf anucleophilicberyllylcomplexviametathesisatbebe2 AT aldridges anucleophilicberyllylcomplexviametathesisatbebe2 AT boronskijt nucleophilicberyllylcomplexviametathesisatbebe2 AT crumptonae nucleophilicberyllylcomplexviametathesisatbebe2 AT roperaf nucleophilicberyllylcomplexviametathesisatbebe2 AT aldridges nucleophilicberyllylcomplexviametathesisatbebe2 |