N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P-P bond and its subsequent reactivity

N-heterocyclic carbene induced reductive coupling of phosphorus tribromide. Isolation of a bromine bridged P-P bond and its subsequent reactivity

The room temperature reaction of a 1 : 1 mixture of phosphorus tribromide (PBr3) and the N-heterocyclic carbene 1,3-bis(2,6-diisopropylphenyl)-imidazol-2-ylidene (IPr) quantitatively affords the Lewis acid-base adduct (IPr)PBr3 (1). Interestingly, when 1 is heated between 55 and 65 °C for a period o...

书目详细资料
Main Authors:	Waters, J, Everitt, T, Myers, W, Goicoechea, J
格式:	Journal article
出版:	Royal Society of Chemistry 2016

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