Acoustic phonons and negative thermal expansion in MOF-5.

Acoustic phonons and negative thermal expansion in MOF-5.

The mechanism of negative thermal expansion (NTE) in MOF-5 has been studied using a rigid unit mode analysis of the phonons responsible for NTE. In addition to confirming the role of the previously proposed optic 'trampoline mode' mechanism [Lock et al., Dalton Trans., 2013, 42, 1933-2320]...

Full description

Bibliographic Details
Main Authors:	Rimmer, L, Dove, M, Goodwin, A, Palmer, D
Format:	Journal article
Language:	English
Published:	Royal Society of Chemistry 2014

Similar Items

Framework flexibility and the negative thermal expansion mechanism of copper(I) oxide Cu2O
by: Rimmer, L, et al.
Published: (2014)

The hydrogen-bonding transition and isotope-dependent negative thermal expansion in H3Co(CN)6.
by: Keen, D, et al.
Published: (2010)

Origin of the colossal positive and negative thermal expansion in Ag(3)[Co(CN)(6)]: an ab initio density functional theory study
by: Calleja, M, et al.
Published: (2008)

Colossal positive and negative thermal expansion in the framework material Ag3[Co(CN)6].
by: Goodwin, A, et al.
Published: (2008)

Phonon dynamics in the layered negative thermal expansion compounds CuxNi2−x(CN)4
by: D’Ambrumenil, S, et al.
Published: (2019)

Negative thermal expansion in ZrW2O8: Mechanisms, rigid unit modes, and neutron total scattering
by: Tucker, MG, et al.
Published: (2005)

Negative hydration expansion in ZrW2O8: microscopic mechanism, spaghetti dynamics, and negative thermal expansion
by: Baise, M, et al.
Published: (2018)

How to quantify isotropic negative thermal expansion: magnitude, range, or both?
by: Goodwin, A, et al.
Published: (2018)

Rigid Unit Modes and the negative thermal expansion in ZrW2O8
by: Pryde, A, et al.
Published: (1997)

Rigid unit modes and the negative thermal expansion in ZrW2O8
by: Pryde, A, et al.
Published: (1997)

Negative thermal expansion and low-frequency modes in cyanide-bridged framework materials
by: Goodwin, A, et al.
Published: (2005)

Nanoporosity and exceptional negative thermal expansion in single-network cadmium cyanide.
by: Phillips, A, et al.
Published: (2008)

Charge-ice dynamics in the negative thermal expansion material Cd(CN)$_2$
by: Fairbank, V, et al.
Published: (2012)

Geometric switching of linear to area negative thermal expansion in uniaxial metal-organic frameworks
by: Collings, I, et al.
Published: (2014)

Symmetry switching of negative thermal expansion by chemical control
by: Senn, M, et al.
Published: (2016)

Argentophilicity-dependent colossal thermal expansion in extended prussian blue analogues.
by: Goodwin, A, et al.
Published: (2008)

Uniaxial negative thermal expansion and metallophilicity in Cu3[Co(CN)6]
by: Sapnik, A, et al.
Published: (2017)

Lightweight Mechanical Metamaterials with Tunable Negative Thermal Expansion
by: Wang, Qiming, et al.
Published: (2016)

Characterization of negative thermal expansion of shape memory alloys
by: Wong, Yu Lian.
Published: (2009)

Phonons from powder diffraction: A quantitative model-independent evaluation
by: Goodwin, A, et al.
Published: (2004)

Negative X-ray expansion in cadmium cyanide
by: Coates, CS, et al.
Published: (2021)

Nanomaterials: The ins and outs of thermal expansion.
by: Goodwin, A
Published: (2008)

Negative Thermal Expansion in Ferromagnetic Fe-Ni Invar Alloys
by: Yusof, Hashim, et al.
Published: (2010)

Review of phononic crystals and acoustic metamaterials
by: Chen, Qiqi, et al.
Published: (2020)

Dynamic DMF Binding in MOF-5 Enables the Formation of Metastable Cobalt-Substituted MOF-5 Analogues
by: Bellarosa, Luca, et al.
Published: (2016)

The reactivity and cation exchange of MOF-5
by: Brozek, Carl Kavanaugh
Published: (2015)

The politics of negative expansion
by: Touzet, C
Published: (2019)

Systematic Simulations of Structural Stability, Phonon Dispersions, and Thermal Expansion in Zinc-Blende ZnO
by: Talwar, Devki N., et al.
Published: (2025)

Anharmonicity and scissoring modes in the negative thermal expansion materials ScF3 and CaZrF6
by: Bird, TA, et al.
Published: (2020)

Local structure in Ag(3)[Co(CN)(6)]: colossal thermal expansion, rigid unit modes and argentophilic interactions
by: Conterio, M, et al.
Published: (2008)

Thermal Cycling of a MOF-Based NO Disproportionation Catalyst
by: Wright, Ashley M., et al.
Published: (2022)

Phonon diodes and transistors from magneto-acoustics
by: Sklan, Sophia Robin, et al.
Published: (2014)

Negative thermal expansion in hybrid improper ferroelectric Ruddlesden-Popper perovskites by symmetry trapping
by: Senn, M, et al.
Published: (2015)

Negative thermal expansion in hybrid improper ferroelectric Ruddlesden-Popper perovskites by symmetry trapping
by: Senn, M, et al.
Published: (2015)

Lifetimes of Confined Acoustic Phonons in Ultrathin Silicon Membranes
by: Cuffe, John, et al.
Published: (2013)

Long mean free paths of room-temperature THz acoustic phonons in a high thermal conductivity material
by: Chou, Ting-Han, et al.
Published: (2021)

Anomalous thermal expansion, negative linear compressibility, and high-pressure phase transition in : Neutron inelastic scattering and lattice dynamics studies
by: Gupta, MK, et al.
Published: (2017)

Thermal expansion /
by: 365586 Yates, Bernard
Published: (1972)

Machine Learning for Phonon Thermal Transport
by: Chen, Zhantao
Published: (2023)

Deviational Phonons and Thermal Transport at the Nanoscale
by: Peraud, Jean-Philippe Michel, et al.
Published: (2017)