Synthesis, structures and reactivity of group 4 hydrazido complexes supported by calix[4]arene ligands.

Synthesis, structures and reactivity of group 4 hydrazido complexes supported by calix[4]arene ligands.

Reaction of TiCl(2)(Me(2)Calix) with 2 equiv of LiNHNRR' afforded the corresponding terminal hydrazido(2-) complexes Ti(NNRR')(Me(2)Calix) (R = Ph, R' = Ph (1) or Me; R = R' = Me (3)) which were all structurally characterized. The X-ray structure of Ph(2)NNH(2) is reported for co...

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Bibliographic Details
Main Authors:	Clulow, A, Selby, J, Cushion, MG, Schwarz, A, Mountford, P
Format:	Journal article
Language:	English
Published:	2008

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